5''-(4-allyloxyphenyl)-3,4'-didecyl-2,2':5',2''-terthiophene

Base Information

• Chemical Name: 5''-(4-allyloxyphenyl)-3,4'-didecyl-2,2':5',2''-terthiophene
• CAS No.: 1423159-66-3
• Molecular Formula: C₄₁H₅₆OS₃
• Molecular Weight: 661.093
• Mol file: 1423159-66-3.mol

Synonyms:5''-(4-allyloxyphenyl)-3,4'-didecyl-2,2':5',2''-terthiophene

Chemical Property of 5''-(4-allyloxyphenyl)-3,4'-didecyl-2,2':5',2''-terthiophene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5''-(4-allyloxyphenyl)-3,4'-didecyl-2,2':5',2''-terthiophene

There total 7 articles about 5''-(4-allyloxyphenyl)-3,4'-didecyl-2,2':5',2''-terthiophene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-decyl magnesium bromide (17049-50-2) → 5''-(4-allyloxyphenyl)-3,4'-didecyl-2,2':5',2''-terthiophene (1423159-66-3)

Guidance literature:

Multi-step reaction with 5 steps

1.1: 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) / tetrahydrofuran / 15 h / Reflux

2.1: N-Bromosuccinimide / tetrahydrofuran / 15 h / 30 °C

3.1: magnesium / tetrahydrofuran / 1 h / 60 °C / Reflux

3.2: 15 h / 0 - 20 °C / Reflux

4.1: boron tribromide / dichloromethane / 12 h / -78 - 20 °C

5.1: potassium carbonate / acetonitrile / 2 h / Inert atmosphere; Reflux

With N-Bromosuccinimide; 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); boron tribromide; potassium carbonate; magnesium; In tetrahydrofuran; dichloromethane; acetonitrile;

DOI:10.1039/c3cc38859j

Reference yield:

5-(4-methoxylphenyl)-2-bromothiophene (54095-24-8) → 5''-(4-allyloxyphenyl)-3,4'-didecyl-2,2':5',2''-terthiophene (1423159-66-3)

Guidance literature:

Multi-step reaction with 5 steps

1.1: magnesium / tetrahydrofuran / 1 h / Reflux

1.2: 15 h / 0 - 20 °C / Reflux

2.1: N-Bromosuccinimide / tetrahydrofuran / 15 h / 30 °C / Inert atmosphere

3.1: magnesium / tetrahydrofuran / 1 h / 60 °C / Reflux

3.2: 15 h / 0 - 20 °C / Reflux

4.1: boron tribromide / dichloromethane / 12 h / -78 - 20 °C

5.1: potassium carbonate / acetonitrile / 2 h / Inert atmosphere; Reflux

With N-Bromosuccinimide; boron tribromide; potassium carbonate; magnesium; In tetrahydrofuran; dichloromethane; acetonitrile;

DOI:10.1039/c3cc38859j

Reference yield:

5-bromo-3-decyl-5'-(4-methoxyphenyl)-2,2'-bithiophene (1423159-63-0) → 5''-(4-allyloxyphenyl)-3,4'-didecyl-2,2':5',2''-terthiophene (1423159-66-3)

Guidance literature:

Multi-step reaction with 3 steps

1.1: magnesium / tetrahydrofuran / 1 h / 60 °C / Reflux

1.2: 15 h / 0 - 20 °C / Reflux

2.1: boron tribromide / dichloromethane / 12 h / -78 - 20 °C

3.1: potassium carbonate / acetonitrile / 2 h / Inert atmosphere; Reflux

With boron tribromide; potassium carbonate; magnesium; In tetrahydrofuran; dichloromethane; acetonitrile;

DOI:10.1039/c3cc38859j

upstream raw materials:

4-methoxyphenylboronic acid

4-[3',3''-dialkyl-(2,2':5',2''-terthiophene)-5-yl]phenol

allyl bromide

n-decyl magnesium bromide

Downstream raw materials:

3-{4-[3',3''-decyl-(2,2':5',2''-terthiophene)-5-yl]phenoxy}propane-1,2-diol