tert-Butyl-((S)-3-methylsulfanylmethoxy-3-(S)-oxiranyl-propoxy)-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-((S)-3-methylsulfanylmethoxy-3-(S)-oxiranyl-propoxy)-diphenyl-silane
CAS No.:549505-00-2
Molecular Formula:C₂₃H₃₂O₃SSi
Molecular Weight:416.657
Hs Code.:

Synonyms:tert-Butyl-((S)-3-methylsulfanylmethoxy-3-(S)-oxiranyl-propoxy)-diphenyl-silane

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Chemical Property of tert-Butyl-((S)-3-methylsulfanylmethoxy-3-(S)-oxiranyl-propoxy)-diphenyl-silane

Chemical Property:

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Technology Process of tert-Butyl-((S)-3-methylsulfanylmethoxy-3-(S)-oxiranyl-propoxy)-diphenyl-silane

There total 7 articles about tert-Butyl-((S)-3-methylsulfanylmethoxy-3-(S)-oxiranyl-propoxy)-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 549505-11-5
Methanesulfonic acid (1R,2S)-4-(tert-butyl-diphenyl-silanyloxy)-1-hydroxymethyl-2-methylsulfanylmethoxy-butyl ester

: 549505-00-2
tert-Butyl-((S)-3-methylsulfanylmethoxy-3-(S)-oxiranyl-propoxy)-diphenyl-silane

Guidance literature:: With potassium carbonate; In methanol; dichloromethane;
DOI:10.1016/S0040-4039(03)00432-5

Reference yield:

: 106183-57-7
5-tert-butyldimethylsilyl ether of (4S,5R)-4-hydroxy-5-hydroxymethyltetrahydrofuran-2-one

: 549505-00-2
tert-Butyl-((S)-3-methylsulfanylmethoxy-3-(S)-oxiranyl-propoxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 6 steps

1: 81 percent / Ac₂O / acetic acid / 70 °C

2: 87 percent / LiBH₄ / diethyl ether

3: imidazole / dimethylformamide

4: pyridine; DMAP / CH₂Cl₂

5: 78 percent / 1N HCl / methanol; tetrahydrofuran

6: 86 percent / K₂CO₃ / methanol; CH₂Cl₂

With pyridine; 1H-imidazole; hydrogenchloride; dmap; lithium borohydride; acetic anhydride; potassium carbonate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; acetic acid; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(03)00432-5

Reference yield:

: 34371-14-7
2-deoxy-D-ribonolactone

: 549505-00-2
tert-Butyl-((S)-3-methylsulfanylmethoxy-3-(S)-oxiranyl-propoxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 7 steps

1: 70 percent / AgNO₃; pyridine / acetonitrile

2: 81 percent / Ac₂O / acetic acid / 70 °C

3: 87 percent / LiBH₄ / diethyl ether

4: imidazole / dimethylformamide

5: pyridine; DMAP / CH₂Cl₂

6: 78 percent / 1N HCl / methanol; tetrahydrofuran

7: 86 percent / K₂CO₃ / methanol; CH₂Cl₂

With pyridine; 1H-imidazole; hydrogenchloride; dmap; lithium borohydride; acetic anhydride; potassium carbonate; silver nitrate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; acetic acid; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0040-4039(03)00432-5