7-{6-bromo-3-[7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl]-quinoxalin-2-yl}-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine

Base Information

• Chemical Name: 7-{6-bromo-3-[7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl]-quinoxalin-2-yl}-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine
• CAS No.: 1217344-01-8
• Molecular Formula: C₈₂H₈₇BrN₄
• Molecular Weight: 1208.52
• Mol file: 1217344-01-8.mol

Synonyms:7-{6-bromo-3-[7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl]-quinoxalin-2-yl}-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine

Chemical Property of 7-{6-bromo-3-[7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl]-quinoxalin-2-yl}-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7-{6-bromo-3-[7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl]-quinoxalin-2-yl}-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine

There total 1 articles about 7-{6-bromo-3-[7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl]-quinoxalin-2-yl}-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.6%

1,2-bis(7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl)ethane-1,2-dione (1217344-00-7) + 4-Bromo-benzene-1,2-diamine (1575-37-7) → 7-{6-bromo-3-[7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl]-quinoxalin-2-yl}-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine (1217344-01-8)

Guidance literature:

With acetic acid; for 6h; Inert atmosphere; Reflux;

DOI:10.1002/chem.201202178

Reference yield: 92.1%

7-{6-bromo-3-[7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl]-quinoxalin-2-yl}-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine (1217344-01-8) + trimethylsilylacetylene (1066-54-2) → 7,7'-{6-[(trimethylsilyl)ethynyl]quinoxaline-2,3-diyl}bis(9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine) (1616971-42-6)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine; In tetrahydrofuran; at 90 ℃; for 21h; Inert atmosphere;

DOI:10.1002/asia.201402094

Reference yield: 92.0%

7-{6-bromo-3-[7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl]-quinoxalin-2-yl}-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine (1217344-01-8) + bis(pinacol)diborane (73183-34-3) → 7,7'-(6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)quinoxaline-2,3-diyl)bis(9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine) (1346520-17-9)

Guidance literature:

With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium acetate; In N,N-dimethyl-formamide; at 70 ℃; for 3h; Inert atmosphere;

DOI:10.1016/j.tetlet.2011.10.019

upstream raw materials:

1,2-bis(7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl)ethane-1,2-dione

4-Bromo-benzene-1,2-diamine

Downstream raw materials:

C₁₆₆H₁₇₆N₈

7-(3-(7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl)-6-vinylquinoxalin-2-yl)-9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine

7,7'-(6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)quinoxaline-2,3-diyl)bis(9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine)

7,7'-[6-({2,3-bis[7-(diphenylamino)-9,9-dihexyl-9H-fluoren-2-yl]quinoxalin-6-yl}amino)quinoxaline-2,3-diyl]bis(9,9-dihexyl-N,N-diphenyl-9H-fluoren-2-amine)