Benzaldehyde, 2-bromo-3,5-bis(phenylmethoxy)-

Base Information

Chemical Name:Benzaldehyde, 2-bromo-3,5-bis(phenylmethoxy)-
CAS No.:85565-94-2
Molecular Formula:C₂₁H₁₇BrO₃
Molecular Weight:397.268
Hs Code.:
DSSTox Substance ID:DTXSID701265707

Synonyms:85565-94-2;Benzaldehyde, 2-bromo-3,5-bis(phenylmethoxy)-;DTXSID701265707;2-Bromo-3,5-bis(phenylmethoxy)benzaldehyde

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Chemical Property of Benzaldehyde, 2-bromo-3,5-bis(phenylmethoxy)-

Chemical Property:

XLogP3:5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:7
Exact Mass:396.03611
Heavy Atom Count:25
Complexity:391

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)COC2=CC(=C(C(=C2)OCC3=CC=CC=C3)Br)C=O

Technology Process of Benzaldehyde, 2-bromo-3,5-bis(phenylmethoxy)-

There total 7 articles about Benzaldehyde, 2-bromo-3,5-bis(phenylmethoxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 67093-26-9
2-bromo-1-(hydroxymethyl)-3,5-bis-(benzyloxy)-benzene

: 85565-94-2
2-bromo-3,5-bis(benzyloxy)benzaldehyde

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; at 25 ℃; for 1.75h;
DOI:10.1021/jo00162a011

Reference yield: 87.0%

: 14615-72-6
3,5-dibenzyloxybenzaldehyde

: 85565-94-2
2-bromo-3,5-bis(benzyloxy)benzaldehyde

Guidance literature:: With N-Bromosuccinimide; In acetonitrile; at 0 - 23 ℃; Inert atmosphere;
DOI:10.1021/acs.orglett.9b00323

Reference yield:

: 2150-44-9
1-carbomethoxy-3,5-dihydroxybenzene

: 85565-94-2
2-bromo-3,5-bis(benzyloxy)benzaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: potassium carbonate / N,N-dimethyl-formamide / 18 h / 20 °C / Inert atmosphere

2: lithium aluminium tetrahydride / tetrahydrofuran / 16.5 h / 0 - 20 °C / Inert atmosphere

3: N-Bromosuccinimide / dichloromethane / 18 h / 0 °C / Inert atmosphere

4: pyridinium chlorochromate / dichloromethane / 16 h / 20 °C / Inert atmosphere

With N-Bromosuccinimide; lithium aluminium tetrahydride; potassium carbonate; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja411146x