Spiro[1,3-dioxolane-2,8'-pentacyclo[5.4.0.0^{2,6}.0^{3,10}.0^{5,9}]undecane]-11'-one

Base Information

Chemical Name:Spiro[1,3-dioxolane-2,8'-pentacyclo[5.4.0.0^{2,6}.0^{3,10}.0^{5,9}]undecane]-11'-one
CAS No.:58228-93-6
Molecular Formula:C₁₃H₁₄O₃
Molecular Weight:218.252
Hs Code.:
NSC Number:177465
DSSTox Substance ID:DTXSID40306558
Nikkaji Number:J1.536.296K

$Spiro[1,3-dioxolane-2,8'-pentacyclo[5.4.0.0^{2,6}.0^{3,10}.0^{5,9}]undecane]-11'-one$

Synonyms:58228-93-6;spiro[1,3-dioxolane-2,8'-pentacyclo[5.4.0.0^{2,6}.0^{3,10}.0^{5,9}]undecane]-11'-one;spiro[1,3-dioxolane-2,11'-pentacyclo[5.4.0.02,6.03,10.05,9]undecane]-8'-one;NSC177465;DTXSID40306558;HMS1726F09;RCL S18261;AKOS001032068;CCG-233232;NSC-177465;SD-220651;CS-0250551;EN300-51316;pentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione monoethylene ketal;spiro[1,3-dioxolane-2,8'-pentacyclo[5.4.0.0?,?.0?,??.0?,?]undecan]-11'-one;spiro[1,3-dioxolane-2,8'-pentacyclo[5.4.0.02,.03,1.0,]undecan]-11'-one

Suppliers and Price of Spiro[1,3-dioxolane-2,8'-pentacyclo[5.4.0.0^{2,6}.0^{3,10}.0^{5,9}]undecane]-11'-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
spiro[1,3-dioxolane-2,8''-pentacyclo[5.4.0.0^{2,6}.0^{3,10}.0^{5,9}]undecane]-11''-one
100mg
$ 265.00

American Custom Chemicals Corporation
SPIRO[1,3-DIOXOLANE-2,8'-PENTACYCLO[5.4.0.0(2,6).0(3,10).0(5,9)]UNDECANE]-11'-ONE 95.00%
5G
$ 2012.49

American Custom Chemicals Corporation
SPIRO[1,3-DIOXOLANE-2,8'-PENTACYCLO[5.4.0.0(2,6).0(3,10).0(5,9)]UNDECANE]-11'-ONE 95.00%
2.5G
$ 1527.20

American Custom Chemicals Corporation
SPIRO[1,3-DIOXOLANE-2,8'-PENTACYCLO[5.4.0.0(2,6).0(3,10).0(5,9)]UNDECANE]-11'-ONE 95.00%
1G
$ 1012.63

Total 6 raw suppliers

Chemical Property of Spiro[1,3-dioxolane-2,8'-pentacyclo[5.4.0.0^{2,6}.0^{3,10}.0^{5,9}]undecane]-11'-one

Chemical Property:

XLogP3:0.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:218.094294304
Heavy Atom Count:16
Complexity:439

Purity/Quality:

97% ^*data from raw suppliers

spiro[1,3-dioxolane-2,8''-pentacyclo[5.4.0.0^{2,6}.0^{3,10}.0^{5,9}]undecane]-11''-one ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1COC2(O1)C3C4CC5C3C(=O)C6C5C4C26

Technology Process of Spiro[1,3-dioxolane-2,8'-pentacyclo[5.4.0.0^{2,6}.0^{3,10}.0^{5,9}]undecane]-11'-one

There total 4 articles about Spiro[1,3-dioxolane-2,8'-pentacyclo[5.4.0.0^{2,6}.0^{3,10}.0^{5,9}]undecane]-11'-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.8%

: 2958-72-7
Cookson's diketone

: 107-21-1
ethylene glycol

: 58228-93-6
pentacyclo<5.4.0.0^2,6.0^3,10.0^5,9>undecane-8,11-dione monoethylene ketal

Guidance literature:: With sulphated zirconia; In toluene; at 80 ℃; for 0.75h;
DOI:10.3390/molecules16086561

Reference yield:

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 58228-93-6
pentacyclo<5.4.0.0^2,6.0^3,10.0^5,9>undecane-8,11-dione monoethylene ketal

Guidance literature:: Multi-step reaction with 3 steps

1: benzene / 1 h / Darkness

2: benzene / 6 h / UV-irradiation

3: toluene-4-sulfonic acid / benzene / 5 h / Reflux; Dean-Stark

With toluene-4-sulfonic acid; In benzene;
DOI:10.1016/j.ejmech.2018.11.051

Reference yield:

: 106-51-4
p-benzoquinone

: 58228-93-6
pentacyclo<5.4.0.0^2,6.0^3,10.0^5,9>undecane-8,11-dione monoethylene ketal

Guidance literature:: Multi-step reaction with 3 steps

1: benzene / 1 h / Darkness

2: benzene / 6 h / UV-irradiation

3: toluene-4-sulfonic acid / benzene / 5 h / Reflux; Dean-Stark

With toluene-4-sulfonic acid; In benzene;
DOI:10.1016/j.ejmech.2018.11.051