tert-butyldimethyl-((1S,6S,8aS)-8a-methyl-6-(2-(phenylsulfinyl)ethoxy)-1,2,3,4,6,7,8,8a-octahydronaphthalen-1-yloxy)silane

Base Information

Chemical Name:tert-butyldimethyl-((1S,6S,8aS)-8a-methyl-6-(2-(phenylsulfinyl)ethoxy)-1,2,3,4,6,7,8,8a-octahydronaphthalen-1-yloxy)silane
CAS No.:943348-11-6
Molecular Formula:C₂₅H₄₀O₃SSi
Molecular Weight:448.742
Hs Code.:

Synonyms:tert-butyldimethyl-((1S,6S,8aS)-8a-methyl-6-(2-(phenylsulfinyl)ethoxy)-1,2,3,4,6,7,8,8a-octahydronaphthalen-1-yloxy)silane

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Chemical Property of tert-butyldimethyl-((1S,6S,8aS)-8a-methyl-6-(2-(phenylsulfinyl)ethoxy)-1,2,3,4,6,7,8,8a-octahydronaphthalen-1-yloxy)silane

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Technology Process of tert-butyldimethyl-((1S,6S,8aS)-8a-methyl-6-(2-(phenylsulfinyl)ethoxy)-1,2,3,4,6,7,8,8a-octahydronaphthalen-1-yloxy)silane

There total 4 articles about tert-butyldimethyl-((1S,6S,8aS)-8a-methyl-6-(2-(phenylsulfinyl)ethoxy)-1,2,3,4,6,7,8,8a-octahydronaphthalen-1-yloxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: C₁₇H₃₂O₂Si

: 20451-53-0
Phenyl vinyl sulfoxide

: 943348-11-6
tert-butyldimethyl-((1S,6S,8aS)-8a-methyl-6-(2-(phenylsulfinyl)ethoxy)-1,2,3,4,6,7,8,8a-octahydronaphthalen-1-yloxy)silane

Guidance literature:: With potassium hydride; sodium hydride; In tetrahydrofuran; at 20 ℃; for 12h;
DOI:10.1021/ol070848t

Reference yield:

: 878-47-7,4242-00-6,34996-06-0,50302-16-4,70191-02-5,34996-05-9
(4aS,5S)-4,4a,5,6,7,8-hexahydro-5-hydroxy-4a-methylnaphthalen-2(3H)-one

: 943348-11-6
tert-butyldimethyl-((1S,6S,8aS)-8a-methyl-6-(2-(phenylsulfinyl)ethoxy)-1,2,3,4,6,7,8,8a-octahydronaphthalen-1-yloxy)silane

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide / 2 h / 20 °C

2: DIBAL-H / CH₂Cl₂

3: 89 percent / KH; NaH / tetrahydrofuran; various solvent(s) / 12 h / 20 °C

With 1H-imidazole; potassium hydride; sodium hydride; diisobutylaluminium hydride; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol070848t

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 943348-11-6
tert-butyldimethyl-((1S,6S,8aS)-8a-methyl-6-(2-(phenylsulfinyl)ethoxy)-1,2,3,4,6,7,8,8a-octahydronaphthalen-1-yloxy)silane

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide / 2 h / 20 °C

2: DIBAL-H / CH₂Cl₂

3: 89 percent / KH; NaH / tetrahydrofuran; various solvent(s) / 12 h / 20 °C

With 1H-imidazole; potassium hydride; sodium hydride; diisobutylaluminium hydride; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol070848t