Chlorobenzene;iodozinc(1+)

Base Information

• Chemical Name: Chlorobenzene;iodozinc(1+)
• CAS No.: 186000-42-0
• Molecular Formula: C₆H₄ClIZn
• Molecular Weight: 303.845
• Hs Code.: 29319090
• DSSTox Substance ID: DTXSID60403396
• Mol file: 186000-42-0.mol

Synonyms:chlorobenzene;iodozinc(1+);3-chlorophenylzinc iodide;186000-42-0;DTXSID60403396

Chemical Property of Chlorobenzene;iodozinc(1+)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 3.02340
• Storage Temp.: 2-8°C
• Sensitive.: Air Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 301.83377
• Heavy Atom Count: 9
• Complexity: 142

Purity/Quality:

99% ^*data from raw suppliers

3-Chlorophenylzinciodide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn
• Statements: 11-19-22-36/37/38-40-36/37
• Safety Statements: 16-26-33-36-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=C[C-]=CC(=C1)Cl.[Zn+]I

Technology Process of Chlorobenzene;iodozinc(1+)

There total 1 articles about Chlorobenzene;iodozinc(1+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-iodochlorobenzene (625-99-0) + zinc (7440-66-6) → (3-chlorophenyl)zinc(II) iodide (186000-42-0)

Guidance literature:

zinc; With lithium chloride; at 150 - 170 ℃; for 2h; Inert atmosphere; Schlenk technique;

With chloro-trimethyl-silane; ethylene dibromide; In tetrahydrofuran; at 20 ℃; Inert atmosphere; Glovebox;

3-iodochlorobenzene; In tetrahydrofuran; for 24h; Inert atmosphere; Glovebox; Reflux;

DOI:10.1021/jacs.8b03163

Reference yield:

4-tolyl iodide (624-31-7) + N,1-diphenylhept-6-en-3-imine + (3-chlorophenyl)zinc(II) iodide (186000-42-0) → C32H32ClN

Guidance literature:

With triphenyl phosphite; nickel dibromide; In acetonitrile; at 60 ℃; for 6h; regioselective reaction; Inert atmosphere; Glovebox; Sealed tube;

DOI:10.1021/jacs.8b03163

Reference yield:

3-methoxy-1-iodobenzene (766-85-8) + 2-methyl-N-phenylhept-6-en-3-imine + (3-chlorophenyl)zinc(II) iodide (186000-42-0) → C27H30ClNO

Guidance literature:

With triphenyl phosphite; nickel dibromide; In acetonitrile; at 60 ℃; for 2h; regioselective reaction; Inert atmosphere; Glovebox; Sealed tube;

DOI:10.1021/jacs.8b03163

upstream raw materials:

3-iodochlorobenzene

zinc

Refernces

• 1、 Kc, Shekhar,Basnet, Prakash,Thapa, Surendra,Shrestha, Bijay,Giri, Ramesh. "Ni-Catalyzed Regioselective Dicarbofunctionalization of Unactivated Olefins by Tandem Cyclization/Cross-Coupling and Application to the Concise Synthesis of Lignan Natural Products". . p. 2920 - 2936. Retrieved 2018/03/09.