[4-Chloro-2-(3-chloro-6-diphenylphosphanyl-2-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane

Base Information

Chemical Name:[4-Chloro-2-(3-chloro-6-diphenylphosphanyl-2-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane
CAS No.:185913-97-7
Molecular Formula:C₃₈H₃₀Cl₂O₂P₂
Molecular Weight:651.509
Hs Code.:
European Community (EC) Number:811-310-8,811-677-4
Nikkaji Number:J2.471.660K,J2.182.860B
Mol file:185913-97-7.mol

Synonyms:185913-98-8;185913-97-7;(S)-(-)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl;[4-chloro-2-(3-chloro-6-diphenylphosphanyl-2-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane;(R)-MeO-Cl-BIPHEP;(r)-(+)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl;MFCD03426987;(R)-(+)-5,5/'-DICHLORO-6,6/'-DIMETHOXY-2,2/'-BIS(DIPHENYLPHOSPHINO)-1,1/'-BIPHENYL;(R)-(-)-Cl-MeO-BIPHEP;(R)-(5,5'-Dichloro-6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine);(S)-(-)-Cl-MeO-BIPHEP;GCBRCSSVOVNEIX-UHFFFAOYSA-N;SCHEMBL1414671;SY068468;SY073807;CS-0086659;CS-0087063;E76943;J-011923;J-011924;5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl;(-)-(5,5'-Dichloro-6,6'-dimethoxy-1,1'-biphenyl)-2,2'-diyl-bis(diphenylphosphine);(-)-2,2'-Bis(diphenylphosphino)-5,5'-dichloro-6,6'-dimethoxy-1,1'-biphenyl;(R)-(+)-5,5'-Dichloro-2,2'-bis(diphenylphosphino)- 6,6'-dimethoxy-1,1'-biphenyl;(R)-(+)-5,5'-Dichloro-2,2'-bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(+)-5,5'-Dichloro-2,2'-bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(R)-(+)-5,5'-Dichloro-2,2'-bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, >=95.0% (H-NMR);(R)-(5,5 inverted exclamation mark -Dichloro-6,6 inverted exclamation mark -dimethoxy-[1,1 inverted exclamation mark -biphenyl]-2,2 inverted exclamation mark -diyl)bis(diphenylphosphine);(S )-(5,5 inverted exclamation mark -Dichloro-6,6 inverted exclamation mark -dimethoxy-[1,1 inverted exclamation mark -biphenyl]-2,2 inverted exclamation mark -diyl)bis(diphenylphosphine);(S)-(-)-5,5'-Dichloro-2,2'-bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, >=97.0% (H-NMR);[3',5-DICHLORO-6'-(DIPHENYLPHOSPHANYL)-2',6-DIMETHOXY-[1,1'-BIPHENYL]-2-YL]DIPHENYLPHOSPHANE

Suppliers and Price of [4-Chloro-2-(3-chloro-6-diphenylphosphanyl-2-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
(R)-(+)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl, min. 95% (R)-Cl-MeO-BIPHEP
1g
$ 354.00

Strem Chemicals
(R)-(+)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl, min. 95% (R)-Cl-MeO-BIPHEP
250mg
$ 101.00

Sigma-Aldrich
(S)-(?)-5,5′-Dichloro-2,2′-bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl ≥97.0% (H-NMR)
1 g
$ 694.00

Sigma-Aldrich
(R)-(+)-5,5′-Dichloro-2,2′-bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl ≥95.0%(H-NMR)
250 mg
$ 217.00

Sigma-Aldrich
(R)-(+)-5,5′-Dichloro-2,2′-bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl ≥95.0% (H-NMR)
250mg-f
$ 217.00

BLDpharm
(R)-(5,5'-Dichloro-6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) 98%
1g
$ 737.00

American Custom Chemicals Corporation
(R)-(+)-5,5'-DICHLORO-6,6'- DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL 95.00%
1G
$ 1321.90

Total 5 raw suppliers

Chemical Property of [4-Chloro-2-(3-chloro-6-diphenylphosphanyl-2-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane

Chemical Property:

Melting Point:176-180 °C
Boiling Point:678.2±55.0 °C(Predicted)
PSA：45.64000
LogP:8.19400
XLogP3:10.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:9
Exact Mass:650.1098096
Heavy Atom Count:44
Complexity:735

Purity/Quality:

95% ^*data from raw suppliers

(R)-(+)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl, min. 95% (R)-Cl-MeO-BIPHEP ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:COC1=C(C=CC(=C1C2=C(C=CC(=C2OC)Cl)P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6)Cl
Description 1. Ligand used in the ruthenium catalyzed, enantioselective hydrogenation of alkenes, carbonyls, and imines. 2. Ligand used in the rhodium-catalyzed cyclization of acetylenic aldehydes. 3. Ligand used in the iridium-catalyzed hydrogenative coupling of alkynes to aromatic and aliphatic N-arylsulfonyl aldimines. 4. Asymmetric Cu-catalyzed propargylic substitution with amines,4a and enamines.4b 5. Catalytic desymmetrizing intramolecular Heck reaction. 6. Assembly of 1,3-polyols. 7. Pd-catalyzed diastereo/enantioselective allylic alkylations of ketone enolates. 8. Enantioselective vinylogous Reformatsky-type addition. 9. Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron- substituted allylcopper complexes. and their In situ site-, diastereo-, and enantioselective additions to ketones.

Technology Process of [4-Chloro-2-(3-chloro-6-diphenylphosphanyl-2-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane

There total 2 articles about [4-Chloro-2-(3-chloro-6-diphenylphosphanyl-2-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%