(1,3-diisopropyl-1H-imidazol-3-ium-2-yl)(phenylthio)dihydroborate

Base Information

• Chemical Name: (1,3-diisopropyl-1H-imidazol-3-ium-2-yl)(phenylthio)dihydroborate
• CAS No.: 1338729-09-1
• Molecular Formula: C₁₅H₂₃BN₂S
• Molecular Weight: 274.238
• Mol file: 1338729-09-1.mol

Synonyms:(1,3-diisopropyl-1H-imidazol-3-ium-2-yl)(phenylthio)dihydroborate

Chemical Property of (1,3-diisopropyl-1H-imidazol-3-ium-2-yl)(phenylthio)dihydroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (1,3-diisopropyl-1H-imidazol-3-ium-2-yl)(phenylthio)dihydroborate

There total 4 articles about (1,3-diisopropyl-1H-imidazol-3-ium-2-yl)(phenylthio)dihydroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

(1,3-diisopropyl-1H-imidazol-3-ium-2-yl)trihydroborate (797056-37-2) + diphenyldisulfane (882-33-7) → (1,3-diisopropyl-1H-imidazol-3-ium-2-yl)(phenylthio)dihydroborate (1338729-09-1) + (1,3-diisopropyl-1H-imidazol-3-ium-2-yl)bis(phenylthio)hydroborate

Guidance literature:

In benzene; at 20 ℃; for 48h; Inert atmosphere; Schlenk technique; Darkness;

DOI:10.1021/ja403627k

Reference yield: 66.0%

(1,3-diisopropyl-1H-imidazol-3-ium-2-yl)trihydroborate (797056-37-2) + diphenyldisulfane (882-33-7) → (1,3-diisopropyl-1H-imidazol-3-ium-2-yl)(phenylthio)dihydroborate (1338729-09-1)

Guidance literature:

Heating;

DOI:10.1002/adsc.201300752

Reference yield: 32.0%

(1,3-diisopropyl-1H-imidazol-3-ium-2-yl)trihydroborate (797056-37-2) + diphenyldisulfane (882-33-7) → (1,3-diisopropyl-1H-imidazol-3-ium-2-yl)(phenylthio)dihydroborate (1338729-09-1) + 1,3-diisopropyl-4-(phenylthio)imidazol-2-ylidene (phenylthio)borane (1338729-08-0) + 1,3-diisopropyl-4,5-bis(phenylthio)imidazol-2-ylidene (phenylthio)borane (1338729-07-9)

Guidance literature:

(1,3-diisopropyl-1H-imidazol-3-ium-2-yl)trihydroborate; With n-butyllithium; In tetrahydrofuran; hexane; at 20 ℃; for 0.0833333h; Inert atmosphere;

diphenyldisulfane; In tetrahydrofuran; hexane; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1021/ol202516c

upstream raw materials:

(1,3-diisopropyl-1H-imidazol-3-ium-2-yl)trihydroborate

diphenyldisulfane