4'-ferrocenyl-4-nitro[1,1']biphenyl

Base Information

Chemical Name:4'-ferrocenyl-4-nitro[1,1']biphenyl
CAS No.:284688-07-9
Molecular Formula:C₂₂H₁₇FeNO₂
Molecular Weight:383.229
Hs Code.:

Synonyms:4'-ferrocenyl-4-nitro[1,1']biphenyl

Suppliers and Price of 4'-ferrocenyl-4-nitro[1,1']biphenyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4'-ferrocenyl-4-nitro[1,1']biphenyl

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4'-ferrocenyl-4-nitro[1,1']biphenyl

There total 2 articles about 4'-ferrocenyl-4-nitro[1,1']biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1274-09-5
bis(ferrocenyl)mercury

: 29170-08-9
4-iodo-4'-nitrobiphenyl

: 284688-07-9
4'-ferrocenyl-4-nitro[1,1']biphenyl

Guidance literature:: With NaI; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; acetone; Fe-complex, ligand and NaI in THF and acetone were placed under Ar, mixt. heated to boiling, Pd-complex was added, refluxed for 1.5 h; filtered, evapd. in vac., column chromy. with benzene-hexane; elem. anal.;
DOI:10.1016/S0022-328X(01)00979-2

Reference yield: 41.0%

: 102-54-5,55404-68-7
ferrocene

: 4'-nitro-4-biphenyldiazonium tetrafluoroborate

: 284688-07-9
4'-ferrocenyl-4-nitro[1,1']biphenyl

Guidance literature:: In acetic acid; 1,2-dichloro-ethane; trifluoroacetic acid; portionwise addn. of addn. of diazonium salt to a soln. of ferrocene in a mixt. of dichloroethane, acetic acid, trifluoroacetic acid at 20°C during 30 min, stirring for 6 h, keeping at 4°C for 18 h; addn. of water and chloroform, sepn. of organic layer, extn. of aq. layer with chloroform, washing the soln. with water until neutral, drying, evapn., chromy. (aluminum oxide, light petroleum followed with 1:2 light petroleum-chloroform); elem. anal.;
DOI:10.1023/A:1023998420937

Reference yield: 90.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: 284688-07-9
4'-ferrocenyl-4-nitro[1,1']biphenyl

: 1210811-81-6
4'-ferrocenyl[1,1' ]biphenyl-4-amine

Guidance literature:: With SnCl₂*2H₂O; NaOH; In hydrogenchloride; mixt. of Fc deriv. , 30% HCl and SnCl2*2H2O stirred under reflux for 3 h; cooled to ambient temp., poured into aq. NaOH soln.; extd. with ether; extracts washed with water, dried over Na2SO4; ether removed in vacuo; dissloolved in CHCl3, filtered through silica gel removed in vacuo; elem. anal.;
DOI:10.1016/j.jorganchem.2009.09.043