4'-ferrocenyl[1,1' ]biphenyl-4-amine

Base Information

Chemical Name:4'-ferrocenyl[1,1' ]biphenyl-4-amine
CAS No.:1210811-81-6
Molecular Formula:C₂₂H₁₉FeN
Molecular Weight:353.247
Hs Code.:

Synonyms:4'-ferrocenyl[1,1' ]biphenyl-4-amine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4'-ferrocenyl[1,1' ]biphenyl-4-amine

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Technology Process of 4'-ferrocenyl[1,1' ]biphenyl-4-amine

There total 2 articles about 4'-ferrocenyl[1,1' ]biphenyl-4-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: 284688-07-9
4'-ferrocenyl-4-nitro[1,1']biphenyl

: 1210811-81-6
4'-ferrocenyl[1,1' ]biphenyl-4-amine

Guidance literature:: With SnCl₂*2H₂O; NaOH; In hydrogenchloride; mixt. of Fc deriv. , 30% HCl and SnCl2*2H2O stirred under reflux for 3 h; cooled to ambient temp., poured into aq. NaOH soln.; extd. with ether; extracts washed with water, dried over Na2SO4; ether removed in vacuo; dissloolved in CHCl3, filtered through silica gel removed in vacuo; elem. anal.;
DOI:10.1016/j.jorganchem.2009.09.043

Reference yield:

: tris(4-ferrocenylphenyl)boroxine

: 540-37-4
p-aminoiodobenzene

: 1210811-81-6
4'-ferrocenyl[1,1' ]biphenyl-4-amine

Guidance literature:: With K₂CO₃; In water; N,N-dimethyl-formamide; to boroxine deriv. in Ar purge sequentially added 4-iodoaniline, K2CO3, DMF, water and Pd complex; react. mixt. stirred in Ar purge at 65-75°C for 3 h; poured into water; extd. from suspn. with CHCl3; extracts washed with water, dried with Na2SO4; CHCl3 removed in vacuo; subjected to column chromy. on silica gel with CH2Cl2 eluent; solvent removed in vacuo;
DOI:10.1016/j.jorganchem.2009.09.043