methyl 3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-α-L-arabino-hexopyranoside

Base Information

Chemical Name:methyl 3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-α-L-arabino-hexopyranoside
CAS No.:103082-83-3
Molecular Formula:C₁₄H₁₆N₄O₆
Molecular Weight:336.304
Hs Code.:

Synonyms:methyl 3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-α-L-arabino-hexopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-α-L-arabino-hexopyranoside

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Technology Process of methyl 3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-α-L-arabino-hexopyranoside

There total 1 articles about methyl 3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-α-L-arabino-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.7%

: 54623-22-2,72002-52-9
methyl-3-azido-2,3,6-tridesoxy-α-L-arabino-hexopyranoside

: 122-04-3
4-nitro-benzoyl chloride

: 103082-83-3
methyl 3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-α-L-arabino-hexopyranoside

Guidance literature:: With pyridine;
DOI:10.1016/S0008-6215(00)90632-3

Reference yield: 68.0%

: 103082-83-3
methyl 3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-α-L-arabino-hexopyranoside

: 3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-L-arabino-hexopyranose

Guidance literature:: With hydrogenchloride; acetic acid; at 80 ℃; for 2.5h;
DOI:10.1016/S0008-6215(00)90632-3

Reference yield:

: 103082-83-3
methyl 3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-α-L-arabino-hexopyranoside

: 103082-90-2
phenyl β-acobioside

Guidance literature:: Multi-step reaction with 5 steps

1: 68 percent / hydrochloric acid-acetic acid / 2.5 h / 80 °C

2: 74 percent / pyridine

3: 1.) molecular sieve type 3A, 2.) trimethylsilyl triflate / 1.) dichloromethane, 1 h, room temperature, 2.) dichloromethane, 4 h, -15 deg C

4: 99.5 percent / sodium methoxide / methanol / 0.05 h / Heating

5: 43 percent / 60 percent acetic acid, hydrogen / 10percent Pd/C / 115 h / 760 Torr / Ambient temperature

With pyridine; hydrogenchloride; trimethylsilyl trifluoromethanesulfonate; 3 A molecular sieve; hydrogen; sodium methylate; acetic acid; palladium on activated charcoal; In methanol;
DOI:10.1016/S0008-6215(00)90632-3