6H-1-(4-nitrophenyl)-2,7,7-trimethyl-4,5,7,8-tetrahydropyrrolo[3,2-c]azepin-4-thione

Base Information

Chemical Name:6H-1-(4-nitrophenyl)-2,7,7-trimethyl-4,5,7,8-tetrahydropyrrolo[3,2-c]azepin-4-thione
CAS No.:267402-07-3
Molecular Formula:C₁₇H₁₉N₃O₂S
Molecular Weight:329.423
Hs Code.:

Synonyms:6H-1-(4-nitrophenyl)-2,7,7-trimethyl-4,5,7,8-tetrahydropyrrolo[3,2-c]azepin-4-thione

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Chemical Property of 6H-1-(4-nitrophenyl)-2,7,7-trimethyl-4,5,7,8-tetrahydropyrrolo[3,2-c]azepin-4-thione

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Technology Process of 6H-1-(4-nitrophenyl)-2,7,7-trimethyl-4,5,7,8-tetrahydropyrrolo[3,2-c]azepin-4-thione

There total 2 articles about 6H-1-(4-nitrophenyl)-2,7,7-trimethyl-4,5,7,8-tetrahydropyrrolo[3,2-c]azepin-4-thione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 267402-00-6
6H-1-(4-nitrophenyl)-2,7,7-trimethyl-4,5,7,8-tetrahydropyrrolo[3,2-c]azepin-4-one

: 267402-07-3
6H-1-(4-nitrophenyl)-2,7,7-trimethyl-4,5,7,8-tetrahydropyrrolo[3,2-c]azepin-4-thione

Guidance literature:: With Lawessons reagent; In toluene; for 1h; Heating;
DOI:10.3987/COM-99-8662

Reference yield:

: 267401-99-0
1-(4-nitrophenyl)-2,6,6-trimethyl-4,5,6,7-tetrahydroindol-4-one oxime

: 267402-07-3
6H-1-(4-nitrophenyl)-2,7,7-trimethyl-4,5,7,8-tetrahydropyrrolo[3,2-c]azepin-4-thione

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / polyphosphoric acid / 1 h / 100 °C

2: 81 percent / Lawesson's reagent / toluene / 1 h / Heating

With Lawessons reagent; PPA; In toluene; 1: Beckmann rearrangement;
DOI:10.3987/COM-99-8662

Reference yield:

: 267402-07-3
6H-1-(4-nitrophenyl)-2,7,7-trimethyl-4,5,7,8-tetrahydropyrrolo[3,2-c]azepin-4-thione

: 267402-13-1
1-(4-nitrophenyl)-2,7,7-trimethyl-4-methylsulfanyl-4,5,7,8-tetrahydropyrrolo[3,2-c]azepine

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂ / 1 h / 20 °C

2: 148 mg / aq. NaHCO₃ / 0.08 h

With sodium hydrogencarbonate; In dichloromethane;
DOI:10.3987/COM-99-8662