1-azido-7-(tert-butyldiphenylsiloxy)-3-(phenylsulfonyl)hepta-3,4-diene

Base Information

Chemical Name:1-azido-7-(tert-butyldiphenylsiloxy)-3-(phenylsulfonyl)hepta-3,4-diene
CAS No.:679002-25-6
Molecular Formula:C₂₉H₃₃N₃O₃SSi
Molecular Weight:531.751
Hs Code.:

Synonyms:1-azido-7-(tert-butyldiphenylsiloxy)-3-(phenylsulfonyl)hepta-3,4-diene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-azido-7-(tert-butyldiphenylsiloxy)-3-(phenylsulfonyl)hepta-3,4-diene

Chemical Property:

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Technology Process of 1-azido-7-(tert-butyldiphenylsiloxy)-3-(phenylsulfonyl)hepta-3,4-diene

There total 5 articles about 1-azido-7-(tert-butyldiphenylsiloxy)-3-(phenylsulfonyl)hepta-3,4-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (7-azido-5-benzenesulfinyl-hepta-3,4-dienyloxy)-tert-butyl-diphenyl-silane

: 679002-25-6
1-azido-7-(tert-butyldiphenylsiloxy)-3-(phenylsulfonyl)hepta-3,4-diene

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃;
DOI:10.1021/jo035729f

Reference yield:

: 112897-03-7
3-(tert-butyldiphenylsilyloxy)-1-propanal

: 679002-25-6
1-azido-7-(tert-butyldiphenylsiloxy)-3-(phenylsulfonyl)hepta-3,4-diene

Guidance literature:: Multi-step reaction with 4 steps

1: LDA / tetrahydrofuran / -78 °C

2: NaN₃ / dimethylformamide / 60 °C

3: Et₃N / tetrahydrofuran / -78 °C

4: m-CPBA / CH₂Cl₂ / 20 °C

With sodium azide; triethylamine; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo035729f

Reference yield:

: 127047-71-6
3-(tert-butyldiphenylsilyloxy)propan-1-ol

: 679002-25-6
1-azido-7-(tert-butyldiphenylsiloxy)-3-(phenylsulfonyl)hepta-3,4-diene

Guidance literature:: Multi-step reaction with 5 steps

1: Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 0 °C

2: LDA / tetrahydrofuran / -78 °C

3: NaN₃ / dimethylformamide / 60 °C

4: Et₃N / tetrahydrofuran / -78 °C

5: m-CPBA / CH₂Cl₂ / 20 °C

With sodium azide; Dess-Martin periodane; triethylamine; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; 1: Dess-Martin oxidation;
DOI:10.1021/jo035729f