(4S,5R,1'R)-3-(phenylfluoren-9-yl)-5-(1'methyl-3'-pentynyl)oxazolidine-4-carboxaldehyde

Base Information

Chemical Name:(4S,5R,1'R)-3-(phenylfluoren-9-yl)-5-(1'methyl-3'-pentynyl)oxazolidine-4-carboxaldehyde
CAS No.:126459-62-9
Molecular Formula:C₂₉H₂₇NO₂
Molecular Weight:421.539
Hs Code.:

Synonyms:(4S,5R,1'R)-3-(phenylfluoren-9-yl)-5-(1'methyl-3'-pentynyl)oxazolidine-4-carboxaldehyde

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Chemical Property of (4S,5R,1'R)-3-(phenylfluoren-9-yl)-5-(1'methyl-3'-pentynyl)oxazolidine-4-carboxaldehyde

Chemical Property:

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Technology Process of (4S,5R,1'R)-3-(phenylfluoren-9-yl)-5-(1'methyl-3'-pentynyl)oxazolidine-4-carboxaldehyde

There total 1 articles about (4S,5R,1'R)-3-(phenylfluoren-9-yl)-5-(1'methyl-3'-pentynyl)oxazolidine-4-carboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 126501-62-0
[(4R,5R)-5-((R)-1-Methyl-pent-3-ynyl)-3-(9-phenyl-9H-fluoren-9-yl)-oxazolidin-4-yl]-methanol

: (4R,5R)-5-((R)-1-Methyl-pent-3-ynyl)-4-methylsulfanylmethoxymethyl-3-(9-phenyl-9H-fluoren-9-yl)-oxazolidine

: 126459-62-9
(4S,5R,1'R)-3-(phenylfluoren-9-yl)-5-(1'methyl-3'-pentynyl)oxazolidine-4-carboxaldehyde

Guidance literature:: Yield given. Multistep reaction;
DOI:10.1021/jo00298a025

Reference yield: 94.0%

: 126459-62-9
(4S,5R,1'R)-3-(phenylfluoren-9-yl)-5-(1'methyl-3'-pentynyl)oxazolidine-4-carboxaldehyde

: 126459-50-5
(4S,5R,1'R)-3-(9-phenylfluoren-9-yl)-5-(1'-methyl-3'-pentynyl)oxazolidine-4-carboxylic acid

Guidance literature:: With sodium chlorite; sodium dihydrogenphosphate; In acetonitrile; tert-butyl alcohol; at 0 ℃; for 0.0833333h;
DOI:10.1021/jo00298a025

Reference yield:

: 126459-62-9
(4S,5R,1'R)-3-(phenylfluoren-9-yl)-5-(1'methyl-3'-pentynyl)oxazolidine-4-carboxaldehyde

: 59865-23-5
(2S,3R,4R,6E)-3-hydroxy-4-methyl-2-methylamino-6-octenoic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 94 percent / NaClO₂, NaH₂PO₄ / acetonitrile; 2-methyl-propan-2-ol; various solvent(s) / 0.08 h / 0 °C

2: 96 percent / NaCNBH₃, CF₃COOH / tetrahydrofuran / 0.33 h / 0 °C

3: 76 percent / Li, liq. NH₃ / 0.03 h / Heating

With sodium chlorite; sodium dihydrogenphosphate; ammonia; lithium; sodium cyanoborohydride; trifluoroacetic acid; In tetrahydrofuran; acetonitrile; tert-butyl alcohol;
DOI:10.1021/jo00298a025