Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-2-methyl-5-oxo-pent-3-enyl ester

Base Information

Chemical Name:Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-2-methyl-5-oxo-pent-3-enyl ester
CAS No.:103563-76-4
Molecular Formula:C₁₆H₂₀O₄
Molecular Weight:276.332
Hs Code.:

Synonyms:Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-2-methyl-5-oxo-pent-3-enyl ester

Suppliers and Price of Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-2-methyl-5-oxo-pent-3-enyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-2-methyl-5-oxo-pent-3-enyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-2-methyl-5-oxo-pent-3-enyl ester

There total 11 articles about Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-2-methyl-5-oxo-pent-3-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 103563-75-3
Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-5-hydroxy-2-methyl-pent-3-enyl ester

: 103563-76-4
Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-2-methyl-5-oxo-pent-3-enyl ester

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; at -78 ℃;
DOI:10.1021/ja00277a028

Reference yield:

: 103563-54-8
(3R,4S)-(E)-7-<(benzyloxy)methoxy>-4-methyl-5-hepten-3-ol

: 103563-76-4
Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-2-methyl-5-oxo-pent-3-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / Ambient temperature

2: 95 percent / PhSH, BF₃*Et₂O / CH₂Cl₂ / Ambient temperature

3: 95 percent / (COCl)2, DMSO, Et₃N / CH₂Cl₂ / -78 °C

With pyridine; oxalyl dichloride; boron trifluoride diethyl etherate; dimethyl sulfoxide; thiophenol; triethylamine; In dichloromethane;
DOI:10.1021/ja00277a028

Reference yield:

: 103563-52-6
(3R,4R)-(Z)-7-<(benzyloxy)methoxy>-4-methyl-5-(trimethylsilyl)-5-hepten-3-ol

: 103563-76-4
Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-2-methyl-5-oxo-pent-3-enyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 96 percent / NaH / hexamethylphosphoric acid triamide / 0.5 h / Ambient temperature

2: pyridine / Ambient temperature

3: 95 percent / PhSH, BF₃*Et₂O / CH₂Cl₂ / Ambient temperature

4: 95 percent / (COCl)2, DMSO, Et₃N / CH₂Cl₂ / -78 °C

With pyridine; oxalyl dichloride; boron trifluoride diethyl etherate; sodium hydride; dimethyl sulfoxide; thiophenol; triethylamine; In N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane;
DOI:10.1021/ja00277a028