Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-5-hydroxy-2-methyl-pent-3-enyl ester

Base Information

Chemical Name:Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-5-hydroxy-2-methyl-pent-3-enyl ester
CAS No.:103563-75-3
Molecular Formula:C₁₆H₂₂O₄
Molecular Weight:278.348
Hs Code.:

Synonyms:Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-5-hydroxy-2-methyl-pent-3-enyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-5-hydroxy-2-methyl-pent-3-enyl ester

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Technology Process of Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-5-hydroxy-2-methyl-pent-3-enyl ester

There total 11 articles about Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-5-hydroxy-2-methyl-pent-3-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: Phenoxy-acetic acid (E)-(1R,2S)-5-benzyloxymethoxy-1-ethyl-2-methyl-pent-3-enyl ester

: 103563-75-3
Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-5-hydroxy-2-methyl-pent-3-enyl ester

Guidance literature:: With boron trifluoride diethyl etherate; thiophenol; In dichloromethane; Ambient temperature;
DOI:10.1021/ja00277a028

Reference yield:

: 103563-52-6
(3R,4R)-(Z)-7-<(benzyloxy)methoxy>-4-methyl-5-(trimethylsilyl)-5-hepten-3-ol

: 103563-75-3
Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-5-hydroxy-2-methyl-pent-3-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / NaH / hexamethylphosphoric acid triamide / 0.5 h / Ambient temperature

2: pyridine / Ambient temperature

3: 95 percent / PhSH, BF₃*Et₂O / CH₂Cl₂ / Ambient temperature

With pyridine; boron trifluoride diethyl etherate; sodium hydride; thiophenol; In N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane;
DOI:10.1021/ja00277a028

Reference yield:

: 103563-51-5
(R)-(Z)-7-<(benzyloxy)methoxy>-4-methyl-5-(trimethylsilyl)-5-hepten-3-one

: 103563-75-3
Phenoxy-acetic acid (E)-(1R,2S)-1-ethyl-5-hydroxy-2-methyl-pent-3-enyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 95 percent / L-selectride / tetrahydrofuran / 0.5 h / -78 °C

2: 96 percent / NaH / hexamethylphosphoric acid triamide / 0.5 h / Ambient temperature

3: pyridine / Ambient temperature

4: 95 percent / PhSH, BF₃*Et₂O / CH₂Cl₂ / Ambient temperature

With pyridine; boron trifluoride diethyl etherate; L-Selectride; sodium hydride; thiophenol; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane;
DOI:10.1021/ja00277a028