((2S,3S,6R,E)-6-ethyl-8-iodooct-4-ene-2,3-diyl)bis(oxy)bis(methylene)dibenzene

Base Information

Chemical Name:((2S,3S,6R,E)-6-ethyl-8-iodooct-4-ene-2,3-diyl)bis(oxy)bis(methylene)dibenzene
CAS No.:1543148-35-1
Molecular Formula:C₂₄H₃₁IO₂
Molecular Weight:478.413
Hs Code.:

Synonyms:((2S,3S,6R,E)-6-ethyl-8-iodooct-4-ene-2,3-diyl)bis(oxy)bis(methylene)dibenzene

Suppliers and Price of ((2S,3S,6R,E)-6-ethyl-8-iodooct-4-ene-2,3-diyl)bis(oxy)bis(methylene)dibenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ((2S,3S,6R,E)-6-ethyl-8-iodooct-4-ene-2,3-diyl)bis(oxy)bis(methylene)dibenzene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ((2S,3S,6R,E)-6-ethyl-8-iodooct-4-ene-2,3-diyl)bis(oxy)bis(methylene)dibenzene

There total 13 articles about ((2S,3S,6R,E)-6-ethyl-8-iodooct-4-ene-2,3-diyl)bis(oxy)bis(methylene)dibenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 1543148-33-9
(2S,3S,6R,E)-3-(benzyloxy)-6-ethyl-8-iodooct-4-en-2-ol

: 100-39-0
benzyl bromide

: 1543148-35-1
((2S,3S,6R,E)-6-ethyl-8-iodooct-4-ene-2,3-diyl)bis(oxy)bis(methylene)dibenzene

Guidance literature:: (2S,3S,6R,E)-3-(benzyloxy)-6-ethyl-8-iodooct-4-en-2-ol; With sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 0.0833333h;

benzyl bromide; With tetra-(n-butyl)ammonium iodide; In tetrahydrofuran; N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 0.166667h;
DOI:10.1016/j.tetlet.2013.12.017

Reference yield:

: 1543148-26-0
(3R,6S,7S,E)-ethyl 6-(benzyloxy)-3-ethyl-7,8-dihydroxyoct-4-enoate

: 1543148-35-1
((2S,3S,6R,E)-6-ethyl-8-iodooct-4-ene-2,3-diyl)bis(oxy)bis(methylene)dibenzene

Guidance literature:: Multi-step reaction with 4 steps

1.1: triethylamine; di(n-butyl)tin oxide / dichloromethane / 0.17 h / 0 °C

1.2: 8 h

2.1: lithium aluminium tetrahydride / tetrahydrofuran / 6 h / 0 - 20 °C

3.1: triphenylphosphine; 1H-imidazole; iodine / dichloromethane / 2 h / 20 °C

4.1: sodium hydride / tetrahydrofuran; N,N-dimethyl-formamide; mineral oil / 0.08 h / 0 °C

4.2: 0.17 h / 0 °C

With 1H-imidazole; lithium aluminium tetrahydride; iodine; sodium hydride; di(n-butyl)tin oxide; triethylamine; triphenylphosphine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1016/j.tetlet.2013.12.017

Reference yield:

: 1543148-32-8
(3R,6S,7S,E)-6-(benzyloxy)-3-ethyloct-4-ene-1,7-diol

: 1543148-35-1
((2S,3S,6R,E)-6-ethyl-8-iodooct-4-ene-2,3-diyl)bis(oxy)bis(methylene)dibenzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: triphenylphosphine; 1H-imidazole; iodine / dichloromethane / 2 h / 20 °C

2.1: sodium hydride / tetrahydrofuran; N,N-dimethyl-formamide; mineral oil / 0.08 h / 0 °C

2.2: 0.17 h / 0 °C

With 1H-imidazole; iodine; sodium hydride; triphenylphosphine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1016/j.tetlet.2013.12.017