(1S,2S)-(E)-1-carboxy-1-(methoxycarbonyl)-2-phenylcyclopropane

Base Information

Chemical Name:(1S,2S)-(E)-1-carboxy-1-(methoxycarbonyl)-2-phenylcyclopropane
CAS No.:180322-77-4
Molecular Formula:C₁₂H₁₂O₄
Molecular Weight:220.225
Hs Code.:

Synonyms:(1S,2S)-(E)-1-carboxy-1-(methoxycarbonyl)-2-phenylcyclopropane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,2S)-(E)-1-carboxy-1-(methoxycarbonyl)-2-phenylcyclopropane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:: SDS file from LookChem

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Technology Process of (1S,2S)-(E)-1-carboxy-1-(methoxycarbonyl)-2-phenylcyclopropane

There total 4 articles about (1S,2S)-(E)-1-carboxy-1-(methoxycarbonyl)-2-phenylcyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 153062-73-8
(1S,2S)-methyl 2β-phenyl-1β-((E)-2-phenylethenyl)cyclopropane-1α-carboxylate

: 180322-77-4
(1S,2S)-(E)-1-carboxy-1-(methoxycarbonyl)-2-phenylcyclopropane

Guidance literature:: With potassium permanganate; sodium periodate; potassium carbonate; In water; tert-butyl alcohol; for 3h; Ambient temperature;
DOI:10.1016/S0040-4039(00)73503-9

Reference yield: 16.0%

: 711011-08-4
(1R,2S)-methyl 2-phenyl-1-{1-{(triisopropylsilyl)oxy}ethenyl}cyclopropanecarboxylate

: 180322-77-4
(1S,2S)-(E)-1-carboxy-1-(methoxycarbonyl)-2-phenylcyclopropane

Guidance literature:: With ozone;
DOI:10.1055/s-2006-926452

Reference yield:

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 711011-05-1
methyl 3-(tri(isopropyl)silanyloxy)-2-diazo-but-3-enoate

: 180322-77-4
(1S,2S)-(E)-1-carboxy-1-(methoxycarbonyl)-2-phenylcyclopropane

: 180322-84-3
monomethyl (1S,2R)-2-phenylcyclopropane-1,1-dicarboxylate

Guidance literature:: styrene; methyl 3-(tri(isopropyl)silanyloxy)-2-diazo-but-3-enoate; With dirhodium(II) tetrakis[N-(1,8-naphthaloyl)-(S)-tert-leucinate]; In toluene; at 0 ℃; for 1h;

With ozone; In methanol; at -78 ℃;

With dimethylsulfide; In methanol; Title compound not separated from byproducts;
DOI:10.1021/ol049554n