180322-84-3Relevant articles and documents
Selectivity enhancement in the Rh(II)-catalyzed cyclopropanation of styrene with (Silanyloxyvinyl)diazoacetates
Muller, Paul,Bernardinelli, Gerald,Allenbach, Yves F.,Ferri, Maria,Flack, Howard D.
, p. 1725 - 1728 (2007/10/03)
Matrix presented. The cyclopropanation of styrene with (silanyloxyvinyl) diazoacetates proceeds with exceptional diastereo- and enantioselectivity in the presence of chiral Rh(II) catalysts. 1,8-Naphthoyl-protected amino acids are the most effective Rh(II) ligands for these transformations.