180322-84-3

Basic information

• Product Name: monomethyl (1S,2R)-2-phenylcyclopropane-1,1-dicarboxylate
• Synonyms: monomethyl (1S,2R)-2-phenylcyclopropane-1,1-dicarboxylate
• CAS NO: 180322-84-3
• Molecular Weight: 220.225
• Mol File: 180322-84-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: monomethyl (1S,2R)-2-phenylcyclopropane-1,1-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: monomethyl (1S,2R)-2-phenylcyclopropane-1,1-dicarboxylate(180322-84-3)
• EPA Substance Registry System: monomethyl (1S,2R)-2-phenylcyclopropane-1,1-dicarboxylate(180322-84-3)

Safety Data

• Hazardous Substances Data: 180322-84-3(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 711011-05-1 methyl 3-(tri(isopropyl)silanyloxy)-2-diazo-but-3-enoate 
• 193079-04-8 methyl (1R,2R)-2-phenyl-1-[(E)-2-phenylvinyl]cyclopropanecarboxylate 

Downstream Products

• 180322-85-4 (1R,2R)-1-tert-Butoxycarbonylamino-2-phenyl-cyclopropanecarboxylic acid methyl ester 
• 180322-86-5 (1R,2R)-1-tert-Butoxycarbonylamino-2-phenyl-cyclopropanecarboxylic acid 
• 180322-87-6 1-(methoxycarbonyl)-2-phenylcyclopropanecarboxylic acid 
• 123806-65-5 methyl (1S,2R)-1-amino-2-phenylcyclopropanecarboxylate 
• 151910-10-0 (1S,2R)-(E)-methyl 1-carbonyl>amino>-2-phenylcyclopropane-1-carboxylate 
• 151910-11-1 (1S,2R)-1--2-phenylcyclopropane-1-carboxylic acid 
• 110716-95-5 1α-amino-2α-phenyl-1β-cyclopropanecarboxylic acid hydrochloride 
• 86087-21-0 (1S,2R)-(E)-(+)-1-amino-2-phenyl-1-cyclopropane-1-carboxylic acid hydrochloride 
• 110769-84-1 methyl (1R,2R)-1-amino-2-phenylcyclopropanecarboxylate 
• 72397-56-9 (2R)-dimethyl 2-phenylcyclopropane-1,1-dicarboxylate 

Relevant articles and documents

Selectivity enhancement in the Rh(II)-catalyzed cyclopropanation of styrene with (Silanyloxyvinyl)diazoacetates

Matrix presented. The cyclopropanation of styrene with (silanyloxyvinyl) diazoacetates proceeds with exceptional diastereo- and enantioselectivity in the presence of chiral Rh(II) catalysts. 1,8-Naphthoyl-protected amino acids are the most effective Rh(II) ligands for these transformations.