180322-84-3

Upstream product

• 100-42-5 styrene 
• 711011-05-1 methyl 3-(tri(isopropyl)silanyloxy)-2-diazo-but-3-enoate 
• 193079-04-8 methyl (1R,2R)-2-phenyl-1-[(E)-2-phenylvinyl]cyclopropanecarboxylate 

Downstream Products

• 180322-85-4 (1R,2R)-1-tert-Butoxycarbonylamino-2-phenyl-cyclopropanecarboxylic acid methyl ester 
• 180322-86-5 (1R,2R)-1-tert-Butoxycarbonylamino-2-phenyl-cyclopropanecarboxylic acid 
• 180322-87-6 1-(methoxycarbonyl)-2-phenylcyclopropanecarboxylic acid 
• 123806-65-5 methyl (1S,2R)-1-amino-2-phenylcyclopropanecarboxylate 
• 151910-10-0 (1S,2R)-(E)-methyl 1-carbonyl>amino>-2-phenylcyclopropane-1-carboxylate 
• 151910-11-1 (1S,2R)-1--2-phenylcyclopropane-1-carboxylic acid 
• 110716-95-5 1α-amino-2α-phenyl-1β-cyclopropanecarboxylic acid hydrochloride 
• 86087-21-0 (1S,2R)-(E)-(+)-1-amino-2-phenyl-1-cyclopropane-1-carboxylic acid hydrochloride 
• 110769-84-1 methyl (1R,2R)-1-amino-2-phenylcyclopropanecarboxylate 
• 72397-56-9 (2R)-dimethyl 2-phenylcyclopropane-1,1-dicarboxylate 

Relevant academic research and scientific papers

Selectivity enhancement in the Rh(II)-catalyzed cyclopropanation of styrene with (Silanyloxyvinyl)diazoacetates

Matrix presented. The cyclopropanation of styrene with (silanyloxyvinyl) diazoacetates proceeds with exceptional diastereo- and enantioselectivity in the presence of chiral Rh(II) catalysts. 1,8-Naphthoyl-protected amino acids are the most effective Rh(II) ligands for these transformations.

Asymmetric cyclopropanations by rhodium(II) N-(arylsulfonyl)prolinate catalyzed decomposition of vinyldiazomethanes in the presence of alkenes. Practical enantioselective synthesis of the four stereoisomers of 2-phenylcyclopropan-1-amino acid

The rhodium N-(arylsulfonyl)prolinate catalyzed decomposition of vinyldiazomethanes in the presence of alkenes leads to a very general method for the synthesis of functionalized cyclopropanes in a highly diastereoselective and enantioselective mode. A det