Phosphinous chloride, (4-methylphenyl)phenyl-

Base Information

Chemical Name:Phosphinous chloride, (4-methylphenyl)phenyl-
CAS No.:1016-80-4
Molecular Formula:C₁₃H₁₂ClP
Molecular Weight:234.665
Hs Code.:
DSSTox Substance ID:DTXSID901254392

Synonyms:Phosphinous chloride, (4-methylphenyl)phenyl-;SCHEMBL2154839;DTXSID901254392;1016-80-4

Suppliers and Price of Phosphinous chloride, (4-methylphenyl)phenyl-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Phosphinous chloride, (4-methylphenyl)phenyl-

Chemical Property:

XLogP3:4.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:234.0365151
Heavy Atom Count:15
Complexity:181

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=C(C=C1)P(C2=CC=CC=C2)Cl

Technology Process of Phosphinous chloride, (4-methylphenyl)phenyl-

There total 10 articles about Phosphinous chloride, (4-methylphenyl)phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.9%

: C₁₇H₂₂NP

: 1016-80-4
chloro-phenyl-p-tolyl-phosphine

Guidance literature:: With hydrogenchloride; In diethyl ether; water; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique;
DOI:10.1016/j.apcata.2018.04.030

Reference yield:

: 644-97-3
Dichlorophenylphosphine

: 1016-80-4
chloro-phenyl-p-tolyl-phosphine

Guidance literature:: In tetrahydrofuran; at 0 ℃; for 1h;
DOI:10.1021/jo0484979

Reference yield:

: 644-97-3
Dichlorophenylphosphine

: 1016-80-4
chloro-phenyl-p-tolyl-phosphine

Guidance literature:: Multi-step reaction with 3 steps

1.1: pyridine / hexane / 3 h / -78 - 20 °C / Inert atmosphere; Schlenk technique

2.1: magnesium / tetrahydrofuran / 45 °C / Inert atmosphere; Schlenk technique

2.2: 3 h / Inert atmosphere; Schlenk technique; Reflux

3.1: hydrogenchloride / diethyl ether; water / 1 h / 20 °C / Inert atmosphere; Schlenk technique

With pyridine; hydrogenchloride; magnesium; In tetrahydrofuran; diethyl ether; hexane; water;
DOI:10.1016/j.apcata.2018.04.030