Methyl 6-deoxy-6-(diphenylphosphino)-2,3,4-tris-O-(trimethylsilyl)hexo pyranoside

Base Information

Chemical Name:Methyl 6-deoxy-6-(diphenylphosphino)-2,3,4-tris-O-(trimethylsilyl)hexo pyranoside
CAS No.:180998-04-3
Molecular Formula:C28H47 O5 P Si3
Molecular Weight:578.908
Hs Code.:

Synonyms:Methyl 6-deoxy-6-(diphenylphosphino)-2,3,4-tris-O-(trimethylsilyl)hexo pyranoside

Suppliers and Price of Methyl 6-deoxy-6-(diphenylphosphino)-2,3,4-tris-O-(trimethylsilyl)hexo pyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl 6-deoxy-6-(diphenylphosphino)-2,3,4-tris-O-(trimethylsilyl)hexo pyranoside

Chemical Property:

PSA：59.74000
LogP:6.15090

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Methyl 6-deoxy-6-(diphenylphosphino)-2,3,4-tris-O-(trimethylsilyl)hexo pyranoside

There total 5 articles about Methyl 6-deoxy-6-(diphenylphosphino)-2,3,4-tris-O-(trimethylsilyl)hexo pyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 65567-06-8,4541-02-0
lithium diphenylphosphide

: 180998-03-2
Toluene-4-sulfonic acid (2R,3R,4S,5R,6S)-6-methoxy-3,4,5-tris-trimethylsilanyloxy-tetrahydro-pyran-2-ylmethyl ester

: 180998-04-3
((2S,3R,4S,5R,6S)-6-Methoxy-3,4,5-tris-trimethylsilanyloxy-tetrahydro-pyran-2-ylmethyl)-diphenyl-phosphane

Guidance literature:: In diethyl ether; for 0.5h; Heating;
DOI:10.1515/znb-1996-0622

Reference yield:

: 180998-03-2
Toluene-4-sulfonic acid (2R,3R,4S,5R,6S)-6-methoxy-3,4,5-tris-trimethylsilanyloxy-tetrahydro-pyran-2-ylmethyl ester

: 20771-10-2,22875-28-1,146399-85-1,4201-65-4
1-O-methyl-2,3,4-tri-O-trimethylsilyl-α-D-glucopyranoside

: 1101-41-3
Tetraphenyldiphosphin

: 180998-04-3
((2S,3R,4S,5R,6S)-6-Methoxy-3,4,5-tris-trimethylsilanyloxy-tetrahydro-pyran-2-ylmethyl)-diphenyl-phosphane

Guidance literature:: With lithium diphenylphosphide; In tetrahydrofuran; at 0 - 10 ℃; for 1h; Yield given;
DOI:10.1515/znb-1996-0622

Reference yield:

: 97-30-3
methyl-alpha-D-glucopyranoside

: 180998-04-3
((2S,3R,4S,5R,6S)-6-Methoxy-3,4,5-tris-trimethylsilanyloxy-tetrahydro-pyran-2-ylmethyl)-diphenyl-phosphane

Guidance literature:: Multi-step reaction with 3 steps

1: 26 percent / pyridine / 48 h / Ambient temperature

2: 89 percent / hexamethyldisilazane, pyridine / 1.) 0 deg C, 15 min, 2.) r.t., 1 h

3: 97 percent / diethyl ether / 0.5 h / Heating

With pyridine; 1,1,1,3,3,3-hexamethyl-disilazane; In diethyl ether;
DOI:10.1515/znb-1996-0622