D-myo-Inositol, 1-O-(4-methoxyphenyl)methyl-2,5,6-tris-O-(phenylmethyl)-, bisbis(phenylmethyl) phosphate

Base Information

Chemical Name:D-myo-Inositol, 1-O-(4-methoxyphenyl)methyl-2,5,6-tris-O-(phenylmethyl)-, bisbis(phenylmethyl) phosphate
CAS No.:180979-79-7
Molecular Formula:C63H64 O13 P2
Molecular Weight:1091.14
Hs Code.:

Synonyms:D-myo-Inositol, 1-O-(4-methoxyphenyl)methyl-2,5,6-tris-O-(phenylmethyl)-, bisbis(phenylmethyl) phosphate

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Chemical Property of D-myo-Inositol, 1-O-(4-methoxyphenyl)methyl-2,5,6-tris-O-(phenylmethyl)-, bisbis(phenylmethyl) phosphate

Chemical Property:

PSA：155.29000
LogP:14.20400

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of D-myo-Inositol, 1-O-(4-methoxyphenyl)methyl-2,5,6-tris-O-(phenylmethyl)-, bisbis(phenylmethyl) phosphate

There total 18 articles about D-myo-Inositol, 1-O-(4-methoxyphenyl)methyl-2,5,6-tris-O-(phenylmethyl)-, bisbis(phenylmethyl) phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 108549-23-1
Dibenzyl N,N-diisopropylphosphoramidite

: 141040-54-2
(+)-2,5,6-tri-O-benzyl-1-O-(p-methoxybenzyl)-myo-inositol

: 180979-79-7
(-)-2,5,6-tri-O-benzyl-1-O-(p-methoxybenzyl)-myo-inositol 3,4-bis(dibenzyl phosphate)

Guidance literature:: Dibenzyl N,N-diisopropylphosphoramidite; With 1H-tetrazole; In dichloromethane; at 23 ℃; for 0.5h;

(+)-2,5,6-tri-O-benzyl-1-O-(p-methoxybenzyl)-myo-inositol; In dichloromethane; at 23 ℃; for 12h;

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -40 ℃; for 0.5h;
DOI:10.1021/jo960602u

Reference yield:

: 187841-49-2
Phosphorous acid dibenzyl ester (1S,2R,3S,4S,5S,6S)-2,3,5-tris-benzyloxy-6-(bis-benzyloxy-phosphanyloxy)-4-(4-methoxy-benzyloxy)-cyclohexyl ester

: 180979-79-7
(-)-2,5,6-tri-O-benzyl-1-O-(p-methoxybenzyl)-myo-inositol 3,4-bis(dibenzyl phosphate)

Guidance literature:: With tert.-butylhydroperoxide; In dichloromethane; acetonitrile; at 0 ℃; Yield given;
DOI:10.1016/S0008-6215(96)00211-X

Reference yield:

: 108549-23-1
Dibenzyl N,N-diisopropylphosphoramidite

: 180979-79-7
(-)-2,5,6-tri-O-benzyl-1-O-(p-methoxybenzyl)-myo-inositol 3,4-bis(dibenzyl phosphate)

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-tetrazole / CH₂Cl₂

2: mCPBA / CH₂Cl₂

With 1H-tetrazole; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;