C₆₉H₉₂O₁₁Si

Base Information

Chemical Name:C₆₉H₉₂O₁₁Si
CAS No.:931113-70-1
Molecular Formula:C₆₉H₉₂O₁₁Si
Molecular Weight:1125.57
Hs Code.:

C<sub>69</sub>H<sub>92</sub>O<sub>11</sub>Si

Synonyms:C₆₉H₉₂O₁₁Si

Suppliers and Price of C₆₉H₉₂O₁₁Si

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₆₉H₉₂O₁₁Si

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₆₉H₉₂O₁₁Si

There total 28 articles about C₆₉H₉₂O₁₁Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 931113-69-8
C₇₅H₁₀₆O₁₁Si₂

: 931113-70-1
C₆₉H₉₂O₁₁Si

Guidance literature:: With acetic acid; In tetrahydrofuran; water; at 20 ℃; for 6h;
DOI:10.1021/jo062513f

Reference yield:

: 871840-51-6
tert-butyldimethyl((4-methylpent-4-en-1-yl)oxy)silane

: 931113-70-1
C₆₉H₉₂O₁₁Si

Guidance literature:: Multi-step reaction with 22 steps

1.1: 36.0 g / (DHQ)2PHAL; K₃[Fe(CN)6]; K₂CO₃ / K₂OsO₂(OH)4 / 2-methyl-propan-2-ol; H₂O / 48 h / 0 °C

2.1: PPTS / CH₂Cl₂ / 1.5 h / 20 °C

3.1: 21.77 g / TBAF / tetrahydrofuran / 2 h / cooling

4.1: 59 percent / Ph₃P; DIAD / tetrahydrofuran / 24 h / 20 °C

5.1: 60 percent / MCPBA / CH₂Cl₂ / 16 h / 20 °C

6.1: 84 percent / KHMDS / 1,2-dimethoxy-ethane; toluene / 2.5 h / -78 - 20 °C

7.1: 90 percent / DIBAL-H / CH₂Cl₂ / 1.5 h / -78 °C

8.1: 96 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂; H₂O / 3 h / 20 °C

9.1: KHMDS / tetrahydrofuran / 0.5 h / -78 °C

9.2: 99 percent / tetrahydrofuran / 1 h / -78 °C

10.1: Hg(OAc)2 / tetrahydrofuran; H₂O / 1 h / cooling

10.2: 72 percent / NaBH₄ / tetrahydrofuran; H₂O / 2 h

11.1: 99 percent / imidazole; DMAP / dimethylformamide / 0.5 h

12.1: 37 percent / PPTS / methanol / 3 h / Heating

13.1: Et₃N; MsCl / CH₂Cl₂ / 0.83 h / 0 °C

13.2: 81 percent / DBU / CH₂Cl₂ / 4 h / 20 °C

14.1: (DHQD)2PHAL; K₃[Fe(CN)6]; K₂CO₃ / potassium osmate dihydrate; K₂S₂O₈ / 2-methyl-propan-2-ol; H₂O / 16 h / cooling

15.1: 91 percent / PPTS / methanol; CH₂Cl₂ / 2.08 h / -78 - 20 °C

16.1: 59 percent / KHMDS / tetrahydrofuran; toluene / 16 h / cooling

17.1: 83 percent / KH / tetrahydrofuran; various solvent(s) / 2 h

18.1: 99 percent / TBAF / tetrahydrofuran / 16 h / 20 °C

19.1: 83 percent / Ph₃P; DIAD / tetrahydrofuran / 0 - 20 °C

20.1: 99 percent / ammonium molibdate trihydrate; hydrogen peroxide / ethanol; H₂O / 16 h / 20 °C

21.1: 43 percent / KHMDS / 1,2-dimethoxy-ethane; toluene / -70 - 0 °C

22.1: 99 percent / AcOH / tetrahydrofuran; H₂O / 6 h / 20 °C

With pyridine; 1H-imidazole; dmap; Hydroquinone 1,4-phthalazinediyl diether; di-isopropyl azodicarboxylate; mercury(II) diacetate; tetrabutyl ammonium fluoride; dihydrogen peroxide; pyridinium p-toluenesulfonate; potassium hydride; potassium hexamethylsilazane; diisobutylaluminium hydride; potassium carbonate; Dess-Martin periodane; acetic acid; methanesulfonyl chloride; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; potassium hexacyanoferrate(III); potassium osmate(VI); dipotassium peroxodisulfate; potassium dioxotetrahydroxoosmate(VI); In tetrahydrofuran; methanol; 1,2-dimethoxyethane; ethanol; dichloromethane; water; N,N-dimethyl-formamide; toluene; tert-butyl alcohol; 4.1: Mitsunobu reaction / 6.1: Julia-Kocienski coupling / 8.1: Dess-Martin oxidation / 9.2: Wittig olefination / 19.1: Mitsunobu reaction / 21.1: Julia-Kocienski coupling;
DOI:10.1021/jo062513f

Reference yield:

: 931113-55-2
(S)-5-(3-(2-(4-methoxyphenyl)-4-methyl-1,3-dioxolan-4-yl)propylsulfonyl)-1-phenyl-1H-tetrazole

: 931113-70-1
C₆₉H₉₂O₁₁Si

Guidance literature:: Multi-step reaction with 17 steps

1.1: 84 percent / KHMDS / 1,2-dimethoxy-ethane; toluene / 2.5 h / -78 - 20 °C

2.1: 90 percent / DIBAL-H / CH₂Cl₂ / 1.5 h / -78 °C

3.1: 96 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂; H₂O / 3 h / 20 °C

4.1: KHMDS / tetrahydrofuran / 0.5 h / -78 °C

4.2: 99 percent / tetrahydrofuran / 1 h / -78 °C

5.1: Hg(OAc)2 / tetrahydrofuran; H₂O / 1 h / cooling

5.2: 72 percent / NaBH₄ / tetrahydrofuran; H₂O / 2 h

6.1: 99 percent / imidazole; DMAP / dimethylformamide / 0.5 h

7.1: 37 percent / PPTS / methanol / 3 h / Heating

8.1: Et₃N; MsCl / CH₂Cl₂ / 0.83 h / 0 °C

8.2: 81 percent / DBU / CH₂Cl₂ / 4 h / 20 °C

9.1: (DHQD)2PHAL; K₃[Fe(CN)6]; K₂CO₃ / potassium osmate dihydrate; K₂S₂O₈ / 2-methyl-propan-2-ol; H₂O / 16 h / cooling

10.1: 91 percent / PPTS / methanol; CH₂Cl₂ / 2.08 h / -78 - 20 °C

11.1: 59 percent / KHMDS / tetrahydrofuran; toluene / 16 h / cooling

12.1: 83 percent / KH / tetrahydrofuran; various solvent(s) / 2 h

13.1: 99 percent / TBAF / tetrahydrofuran / 16 h / 20 °C

14.1: 83 percent / Ph₃P; DIAD / tetrahydrofuran / 0 - 20 °C

15.1: 99 percent / ammonium molibdate trihydrate; hydrogen peroxide / ethanol; H₂O / 16 h / 20 °C

16.1: 43 percent / KHMDS / 1,2-dimethoxy-ethane; toluene / -70 - 0 °C

17.1: 99 percent / AcOH / tetrahydrofuran; H₂O / 6 h / 20 °C

With pyridine; 1H-imidazole; dmap; di-isopropyl azodicarboxylate; mercury(II) diacetate; tetrabutyl ammonium fluoride; dihydrogen peroxide; pyridinium p-toluenesulfonate; potassium hydride; potassium hexamethylsilazane; diisobutylaluminium hydride; potassium carbonate; Dess-Martin periodane; acetic acid; methanesulfonyl chloride; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; triphenylphosphine; potassium hexacyanoferrate(III); potassium osmate(VI); dipotassium peroxodisulfate; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; ethanol; dichloromethane; water; N,N-dimethyl-formamide; toluene; tert-butyl alcohol; 1.1: Julia-Kocienski coupling / 3.1: Dess-Martin oxidation / 4.2: Wittig olefination / 14.1: Mitsunobu reaction / 16.1: Julia-Kocienski coupling;
DOI:10.1021/jo062513f