carbonic acid tert-butyl ester 1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

Base Information

Chemical Name:carbonic acid tert-butyl ester 1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester
CAS No.:410077-35-9
Molecular Formula:C₂₇H₃₈O₄Si
Molecular Weight:454.682
Hs Code.:

carbonic acid <i>tert</i>-butyl ester 1-(<i>tert</i>-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

Synonyms:carbonic acid tert-butyl ester 1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

Suppliers and Price of carbonic acid tert-butyl ester 1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of carbonic acid tert-butyl ester 1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of carbonic acid tert-butyl ester 1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

There total 2 articles about carbonic acid tert-butyl ester 1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 24424-99-5
di-tert-butyl dicarbonate

: 410077-69-9
1-(tert-butyl-diphenyl-silanyloxy)-2-methyl-pent-4-en-2-ol

: 410077-35-9
carbonic acid tert-butyl ester 1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

Guidance literature:: 1-(tert-butyl-diphenyl-silanyloxy)-2-methyl-pent-4-en-2-ol; With sodium hexamethyldisilazane; In tetrahydrofuran; at 0 ℃; for 0.5h;

di-tert-butyl dicarbonate; In tetrahydrofuran; at 20 ℃; for 1h; Further stages.;
DOI:10.1021/ol017273z

Reference yield:

: 184091-30-3
(S)-1-(tert-butyldiphenylsilyloxy)methyl-1-methyloxirane

: 410077-35-9
carbonic acid tert-butyl ester 1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: CuI / tetrahydrofuran / 1 h / -40 °C

1.2: 83 percent / tetrahydrofuran / -45 - 0 °C

2.1: NaHMDS / tetrahydrofuran / 0.5 h / 0 °C

2.2: 99 percent / tetrahydrofuran / 1 h / 20 °C

With copper(l) iodide; sodium hexamethyldisilazane; In tetrahydrofuran;
DOI:10.1021/ol017273z

Reference yield: 78.0%

: 410077-35-9
carbonic acid tert-butyl ester 1-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-but-3-enyl ester

: 410077-37-1
(4S,6R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-6-iodomethyl-4-methyl-[1,3]dioxan-2-one

: (4S,6S)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-6-iodomethyl-4-methyl-[1,3]dioxan-2-one

Guidance literature:: With iodine(I) bromide; In diethyl ether; dichloromethane; at -100 - -78 ℃; for 5.5h; optical yield given as %de; Inert atmosphere;
DOI:10.1016/j.tet.2009.04.003