1-Fluoro-2-methylazulene

Base Information

Chemical Name:1-Fluoro-2-methylazulene
CAS No.:180129-07-1
Molecular Formula:C₁₁H₉F
Molecular Weight:160.191
Hs Code.:
DSSTox Substance ID:DTXSID20570573
Nikkaji Number:J677.106H
Mol file:180129-07-1.mol

Synonyms:1-fluoro-2-methylazulene;180129-07-1;DTXSID20570573

Suppliers and Price of 1-Fluoro-2-methylazulene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 1-Fluoro-2-methylazulene

Chemical Property:

PSA：0.00000
LogP:3.23890
XLogP3:3.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:160.068828449
Heavy Atom Count:12
Complexity:155

Purity/Quality:: 99%+ ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC2=CC=CC=CC2=C1F

Technology Process of 1-Fluoro-2-methylazulene

There total 4 articles about 1-Fluoro-2-methylazulene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 163807-88-3
methyl 3-fluoro-2-methylazulene-1-carboxylate

: 180129-07-1
1-fluoro-2-methylazulene

Guidance literature:: With peroxomonophosphoric acid; at 90 ℃; for 0.75h;
DOI:10.1246/bcsj.69.1645

Reference yield: 40.0%

: 769-86-8
2-methylazulene

: 180129-07-1
1-fluoro-2-methylazulene

: 1,3-difluoro-2-methylazulene

Guidance literature:: With 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate; In acetonitrile; for 6h; Heating;
DOI:10.1246/cl.1995.169

Reference yield:

: 50603-71-9
3-methoxycarbonyl-2H-cyclohepta[b]furan-2-one

: 180129-07-1
1-fluoro-2-methylazulene

Guidance literature:: Multi-step reaction with 3 steps

1: 62 percent / diethylamine / 72 h / Heating

2: 30 percent / N-fluoro-2,4,6-trimethylpyridinium tetrafluoroborate / acetonitrile / 5 h

3: 99 percent / H₃PO₅ / 0.75 h / 90 °C

With peroxomonophosphoric acid; 1-fluoro-2,4,6-trimethylpyridin-1-ium tetrafluoroborate; diethylamine; In acetonitrile;
DOI:10.1246/bcsj.69.1645