5-(R)-hydroxy-2-(R)-phenyl-[1,3]dioxane-4-(S)-carbaldehyde O-methyl-oxime

Base Information

Chemical Name:5-(R)-hydroxy-2-(R)-phenyl-[1,3]dioxane-4-(S)-carbaldehyde O-methyl-oxime
CAS No.:501373-22-4
Molecular Formula:C₁₂H₁₅NO₄
Molecular Weight:237.255
Hs Code.:

Synonyms:5-(R)-hydroxy-2-(R)-phenyl-[1,3]dioxane-4-(S)-carbaldehyde O-methyl-oxime

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Chemical Property of 5-(R)-hydroxy-2-(R)-phenyl-[1,3]dioxane-4-(S)-carbaldehyde O-methyl-oxime

Chemical Property:

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Technology Process of 5-(R)-hydroxy-2-(R)-phenyl-[1,3]dioxane-4-(S)-carbaldehyde O-methyl-oxime

There total 2 articles about 5-(R)-hydroxy-2-(R)-phenyl-[1,3]dioxane-4-(S)-carbaldehyde O-methyl-oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 593-56-6
N-methoxylamine hydrochloride

: 81577-69-7
[2R,4R,5R]-5-hydroxy-2-phenyl-[1,3]dioxane-4-carbaldehyde

: 501373-22-4
5-(R)-hydroxy-2-(R)-phenyl-[1,3]dioxane-4-(S)-carbaldehyde O-methyl-oxime

: 5-(R)-hydroxy-2-(R)-phenyl-[1,3]dioxane-4-(S)-carbaldehyde O-methyl-oxime

Guidance literature:: With pyridine; In methanol; for 5.5h; Title compound not separated from byproducts; Heating;
DOI:10.1016/j.tetasy.2003.07.013

Reference yield:

: 3006-41-5,20771-09-9,25152-90-3,97232-16-1,104022-77-7,113566-67-9,113566-68-0
4,6-O-benzylidene-D-glucose

: 501373-22-4
5-(R)-hydroxy-2-(R)-phenyl-[1,3]dioxane-4-(S)-carbaldehyde O-methyl-oxime

Guidance literature:: Multi-step reaction with 2 steps

1: NaIO₄; aq. NaOH

2: pyridine / methanol / 5.5 h / Heating

With pyridine; sodium hydroxide; sodium periodate; In methanol;
DOI:10.1016/j.tetasy.2003.07.013

Reference yield:

: 501373-22-4
5-(R)-hydroxy-2-(R)-phenyl-[1,3]dioxane-4-(S)-carbaldehyde O-methyl-oxime

: N-(6-imidazol-1-yl-2-phenyl-tetrahydro-furo[3,2-d][1,3]dioxin-7-yl)-O-methyl-hydroxylamine

Guidance literature:: Multi-step reaction with 2 steps

1: DMAP / tetrahydrofuran / 19.5 h / Heating

2: Ph₃SnH; AIBN / benzene / 3.75 h / 90 °C

With dmap; 2,2'-azobis(isobutyronitrile); triphenylstannane; In tetrahydrofuran; benzene; 2: Barton-McCombie reaction;
DOI:10.1021/ja028617z