[Os₃(CO)₈(μ-pyrimidine-2-thiolate)(μ-H)(μ-bis(diphenylphosphino)methane)]

Base Information

Chemical Name:[Os₃(CO)₈(μ-pyrimidine-2-thiolate)(μ-H)(μ-bis(diphenylphosphino)methane)]
CAS No.:329358-32-9
Molecular Formula:C₃₇H₂₆N₂O₈Os₃P₂S
Molecular Weight:1291.24
Hs Code.:

[Os<sub>3</sub>(CO)<sub>8</sub>(μ-pyrimidine-2-thiolate)(μ-H)(μ-bis(diphenylphosphino)methane)]

Synonyms:[Os₃(CO)₈(μ-pyrimidine-2-thiolate)(μ-H)(μ-bis(diphenylphosphino)methane)]

Suppliers and Price of [Os₃(CO)₈(μ-pyrimidine-2-thiolate)(μ-H)(μ-bis(diphenylphosphino)methane)]

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Chemical Property of [Os₃(CO)₈(μ-pyrimidine-2-thiolate)(μ-H)(μ-bis(diphenylphosphino)methane)]

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Technology Process of [Os₃(CO)₈(μ-pyrimidine-2-thiolate)(μ-H)(μ-bis(diphenylphosphino)methane)]

There total 3 articles about [Os₃(CO)₈(μ-pyrimidine-2-thiolate)(μ-H)(μ-bis(diphenylphosphino)methane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: [(μ-H)(CO)8(Ph2PCH2P(Ph)C6H4)]

: 131242-36-9
2-sulfanylpyrimidine

: 329358-32-9
[Os₃(CO)₈(μ-pyrimidine-2-thiolate)(μ-H)(μ-bis(diphenylphosphino)methane)]

Guidance literature:: In dichloromethane; (N2); standard Schlenk technique; pymSH added to soln. of Os complex in CH2Cl2; stirred at room temp. for 72 h; solvent removed under reduced pressure; chromd. by TLC (SiO2, hexane/CH2Cl2, 7/3); recrystd. (hexane/CH2Cl2, room temp.); elem. anal.;
DOI:10.1016/S0022-328X(00)00696-3

Reference yield: 45.0%

: [(μ-H)(CO)8(Ph2PCH2P(Ph)C6H4)]

: 131242-36-9
2-sulfanylpyrimidine

: 91311-62-5
[Os3(CO)10(μ-bis(diphenylphosphino)methane)]

: 329358-32-9
[Os₃(CO)₈(μ-pyrimidine-2-thiolate)(μ-H)(μ-bis(diphenylphosphino)methane)]

Guidance literature:: In benzene; (N2); standard Schlenk technique; pymSH added to soln. of Os complex in benzene; refluxed for 3 h; solvent removed under reduced pressure; chromd. by TLC (SiO2, hexane/CH2Cl2, 7/3); recrystd. (hexane/CH2Cl2, -20°C);
DOI:10.1016/S0022-328X(00)00696-3