1,4-Benzodioxin-5-carboxylicacid,6-amino-2,3-dihydro-,methylester(9CI)

Base Information

Chemical Name:1,4-Benzodioxin-5-carboxylicacid,6-amino-2,3-dihydro-,methylester(9CI)
CAS No.:179262-62-5
Molecular Formula:C₁₀H₁₁NO₄
Molecular Weight:209.202
Hs Code.:
Mol file:179262-62-5.mol

Synonyms:1,4-Benzodioxin-5-carboxylicacid,6-amino-2,3-dihydro-,methylester(9CI)

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Chemical Property of 1,4-Benzodioxin-5-carboxylicacid,6-amino-2,3-dihydro-,methylester(9CI)

Chemical Property:

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Technology Process of 1,4-Benzodioxin-5-carboxylicacid,6-amino-2,3-dihydro-,methylester(9CI)

There total 10 articles about 1,4-Benzodioxin-5-carboxylicacid,6-amino-2,3-dihydro-,methylester(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 6-nitro-2,3-dihydrobenzo-[b][1,4]-dioxin-5-carboxylate

: 179262-62-5
6-amino-2,3-dihydrobenzo-[b][1,4]-dioxin-5-carboxylate

Guidance literature:: With palladium on activated charcoal; hydrogen; In methanol;

Reference yield:

: N-(5-iodo-2,3-dihydro-1,4-benzodioxin-6-yl)-2,2-dimethylpropanamide

: 179262-62-5
6-amino-2,3-dihydrobenzo-[b][1,4]-dioxin-5-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1-methyl-pyrrolidin-2-one / 85 h / 60 °C

2.1: hydrogenchloride; water / Heating

2.2: Acidic conditions

With hydrogenchloride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; water; In 1-methyl-pyrrolidin-2-one;
DOI:10.1016/j.mencom.2012.11.001

Reference yield:

: 301307-05-1
N-(2,3-dihydro-1,4-benzodioxin-6-yl)-2,2-dimethylpropanamide

: 179262-62-5
6-amino-2,3-dihydrobenzo-[b][1,4]-dioxin-5-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: tert.-butyl lithium / tetrahydrofuran / -100 °C

2.1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1-methyl-pyrrolidin-2-one / 85 h / 60 °C

3.1: hydrogenchloride; water / Heating

3.2: Acidic conditions

With hydrogenchloride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; water; tert.-butyl lithium; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one;
DOI:10.1016/j.mencom.2012.11.001