Bicyclo[2.2.1]heptan-1-amine, 3,3-dimethyl-2-methylene-, (1R,4R)- (9CI)

Base Information

Chemical Name:Bicyclo[2.2.1]heptan-1-amine, 3,3-dimethyl-2-methylene-, (1R,4R)- (9CI)
CAS No.:178603-05-9
Molecular Formula:C₁₀H₁₇N
Molecular Weight:151.252
Hs Code.:
Mol file:178603-05-9.mol

Synonyms:Bicyclo[2.2.1]heptan-1-amine,3,3-dimethyl-2-methylene-, (1R)-

Suppliers and Price of Bicyclo[2.2.1]heptan-1-amine, 3,3-dimethyl-2-methylene-, (1R,4R)- (9CI)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bicyclo[2.2.1]heptan-1-amine, 3,3-dimethyl-2-methylene-, (1R,4R)- (9CI)

Chemical Property:

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Technology Process of Bicyclo[2.2.1]heptan-1-amine, 3,3-dimethyl-2-methylene-, (1R,4R)- (9CI)

There total 9 articles about Bicyclo[2.2.1]heptan-1-amine, 3,3-dimethyl-2-methylene-, (1R,4R)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 178603-04-8
N-((1R,4R)-3,3-Dimethyl-2-methylene-bicyclo[2.2.1]hept-1-yl)-acetamide

: 13487-72-4,178603-05-9
(1R)-3,3-dimethyl-2-methyliden-1-norbornylamine

Guidance literature:: With potassium hydroxide; In diethylene glycol; at 180 ℃; for 24h;
DOI:10.1016/0957-4166(96)00136-X

Reference yield:

: (1S,4S)-3,3-Dimethyl-2-methylene-1-nitro-bicyclo[2.2.1]heptane

: 13487-72-4,178603-05-9
1-Aminocamphen

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether;
DOI:10.1021/jo00807a014

Reference yield:

: 464-49-3,68546-28-1
(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

: 13487-72-4,178603-05-9
(1R)-3,3-dimethyl-2-methyliden-1-norbornylamine

Guidance literature:: Multi-step reaction with 2 steps

1: diisobutyl-(2,4-dimethylpentane-3-yl)amine / CH₂Cl₂ / 24 h / Ambient temperature

2: 1.) Et₃N, MeCN, 2.) KOH, DEG / 1.) 180 deg C, 95 h, 2.) 180 deg C, 48 h

With potassium hydroxide; N,N-diisobutyl-2,4-dimethyl-3-pentylamine; triethylamine; acetonitrile; diethylene glycol; In dichloromethane;
DOI:10.1016/0957-4166(96)00264-9