((E)-(2R,6R)-7-Benzyloxy-2,4,6-trimethyl-hept-3-enyloxy)-tert-butyl-dimethyl-silane

Base Information

Chemical Name:((E)-(2R,6R)-7-Benzyloxy-2,4,6-trimethyl-hept-3-enyloxy)-tert-butyl-dimethyl-silane
CAS No.:89459-70-1
Molecular Formula:C₂₃H₄₀O₂Si
Molecular Weight:376.655
Hs Code.:

Synonyms:((E)-(2R,6R)-7-Benzyloxy-2,4,6-trimethyl-hept-3-enyloxy)-tert-butyl-dimethyl-silane

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Chemical Property of ((E)-(2R,6R)-7-Benzyloxy-2,4,6-trimethyl-hept-3-enyloxy)-tert-butyl-dimethyl-silane

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Technology Process of ((E)-(2R,6R)-7-Benzyloxy-2,4,6-trimethyl-hept-3-enyloxy)-tert-butyl-dimethyl-silane

There total 6 articles about ((E)-(2R,6R)-7-Benzyloxy-2,4,6-trimethyl-hept-3-enyloxy)-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 100-39-0
benzyl bromide

: 89459-68-7
(E)-(2R,6R)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-hept-4-en-1-ol

: 89459-70-1
((E)-(2R,6R)-7-Benzyloxy-2,4,6-trimethyl-hept-3-enyloxy)-tert-butyl-dimethyl-silane

Guidance literature:: With sodium hydride; In tetrahydrofuran; Heating;
DOI:10.1016/S0040-4039(00)99851-4

Reference yield:

: 113489-80-8
(2R^*,3R^*)-1-<(tert-butyldimethylsilyl)oxy>-2,4-dimethyl-4-penten-3-ol

: 89459-70-1
((E)-(2R,6R)-7-Benzyloxy-2,4,6-trimethyl-hept-3-enyloxy)-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: 93 percent / pyridine / CH₂Cl₂

2: 63 percent / Claisen rearrangement by the method of Ireland_.

3: 64 percent / lithium aluminum hydride / diethyl ether / Heating

4: 95 percent / NaH / tetrahydrofuran / Heating

With pyridine; lithium aluminium tetrahydride; sodium hydride; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1016/S0040-4039(00)99851-4

Reference yield:

: 113489-97-7
(2S^*,3S^*)-1-<(tert-butyldimethylsilyl)oxy>-2,4-dimethyl-4-penten-3-yl propanoate

: 89459-70-1
((E)-(2R,6R)-7-Benzyloxy-2,4,6-trimethyl-hept-3-enyloxy)-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 63 percent / Claisen rearrangement by the method of Ireland_.

2: 64 percent / lithium aluminum hydride / diethyl ether / Heating

3: 95 percent / NaH / tetrahydrofuran / Heating

With lithium aluminium tetrahydride; sodium hydride; In tetrahydrofuran; diethyl ether;
DOI:10.1016/S0040-4039(00)99851-4