[(E)-(1R,4R)-1-((E)-(R)-6-Benzyloxy-1-methyl-hex-2-enyl)-2,4-dimethyl-hept-2-enyloxy]-tert-butyl-dimethyl-silane

Base Information

Chemical Name:[(E)-(1R,4R)-1-((E)-(R)-6-Benzyloxy-1-methyl-hex-2-enyl)-2,4-dimethyl-hept-2-enyloxy]-tert-butyl-dimethyl-silane
CAS No.:1026590-46-4
Molecular Formula:C₂₉H₅₀O₂Si
Molecular Weight:458.8
Hs Code.:

Synonyms:[(E)-(1R,4R)-1-((E)-(R)-6-Benzyloxy-1-methyl-hex-2-enyl)-2,4-dimethyl-hept-2-enyloxy]-tert-butyl-dimethyl-silane

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Chemical Property of [(E)-(1R,4R)-1-((E)-(R)-6-Benzyloxy-1-methyl-hex-2-enyl)-2,4-dimethyl-hept-2-enyloxy]-tert-butyl-dimethyl-silane

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Technology Process of [(E)-(1R,4R)-1-((E)-(R)-6-Benzyloxy-1-methyl-hex-2-enyl)-2,4-dimethyl-hept-2-enyloxy]-tert-butyl-dimethyl-silane

There total 15 articles about [(E)-(1R,4R)-1-((E)-(R)-6-Benzyloxy-1-methyl-hex-2-enyl)-2,4-dimethyl-hept-2-enyloxy]-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 628293-09-4
(4E,6R,7R,8E,10R)-1-benzyloxy-6,8,10-trimethyltrideca-4,8-dien-7-ol

: 1026590-46-4
[(E)-(1R,4R)-1-((E)-(R)-6-Benzyloxy-1-methyl-hex-2-enyl)-2,4-dimethyl-hept-2-enyloxy]-tert-butyl-dimethyl-silane

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at -78 ℃;
DOI:10.1021/ol035177n

Reference yield:

: 628293-06-1
(E)-(4R,7R,8R)-13-benzyloxy-7-methoxymethoxy-4,6,8-trimethyltridec-5-en-9-yn-2-one

: 1026590-46-4
[(E)-(1R,4R)-1-((E)-(R)-6-Benzyloxy-1-methyl-hex-2-enyl)-2,4-dimethyl-hept-2-enyloxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 6 steps

1: 98 percent / Dibal-H / diethyl ether; hexane / 2 h / -78 °C

2: i-Pr₂NEt / CH₂Cl₂ / 2 h / 0 °C

3: 291 mg / LiAlH₄ / tetrahydrofuran / 3 h / Heating

4: 85 percent / p-TsOH*H₂O / methanol / 96 h / 20 °C

5: 61 percent / LiAlH₄ / tetrahydrofuran / 72 h / Heating

6: 2,6-lutidine / CH₂Cl₂ / 3 h / -78 °C

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane;
DOI:10.1021/jo0496042

Reference yield:

: 725724-80-1
(2RS,4R,5E,7R,8R)-13-benzyloxy-7-methoxymethoxy-4,6,8-trimethyltridec-5-en-9-yn-2-ol

: 1026590-46-4
[(E)-(1R,4R)-1-((E)-(R)-6-Benzyloxy-1-methyl-hex-2-enyl)-2,4-dimethyl-hept-2-enyloxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 5 steps

1: i-Pr₂NEt / CH₂Cl₂ / 2 h / 0 °C

2: 291 mg / LiAlH₄ / tetrahydrofuran / 3 h / Heating

3: 85 percent / p-TsOH*H₂O / methanol / 96 h / 20 °C

4: 61 percent / LiAlH₄ / tetrahydrofuran / 72 h / Heating

5: 2,6-lutidine / CH₂Cl₂ / 3 h / -78 °C

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; toluene-4-sulfonic acid; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/jo0496042