methyl N-{2-[(E)-2-(phenylsulfonyl)vinyl]phenyl}-N-[(2-pyridyl)sulfonyl]glycinate

Base Information

Chemical Name:methyl N-{2-[(E)-2-(phenylsulfonyl)vinyl]phenyl}-N-[(2-pyridyl)sulfonyl]glycinate
CAS No.:1352965-57-1
Molecular Formula:C₂₂H₂₀N₂O₆S₂
Molecular Weight:472.543
Hs Code.:

Synonyms:methyl N-{2-[(E)-2-(phenylsulfonyl)vinyl]phenyl}-N-[(2-pyridyl)sulfonyl]glycinate

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Chemical Property of methyl N-{2-[(E)-2-(phenylsulfonyl)vinyl]phenyl}-N-[(2-pyridyl)sulfonyl]glycinate

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Technology Process of methyl N-{2-[(E)-2-(phenylsulfonyl)vinyl]phenyl}-N-[(2-pyridyl)sulfonyl]glycinate

There total 4 articles about methyl N-{2-[(E)-2-(phenylsulfonyl)vinyl]phenyl}-N-[(2-pyridyl)sulfonyl]glycinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 5535-48-8
PVS

: 1352965-47-9
methyl N-phenyl-N-[(2-pyridyl)sulfonyl]glycinate

: 1352965-57-1
methyl N-{2-[(E)-2-(phenylsulfonyl)vinyl]phenyl}-N-[(2-pyridyl)sulfonyl]glycinate

Guidance literature:: With palladium diacetate; 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate; In 1,1-dichloroethane; at 110 ℃; for 18h; regiospecific reaction; Inert atmosphere;
DOI:10.1002/anie.201105611

Reference yield:

: 2637-34-5,73018-10-7
2-Sulfanylpyridine

: 1352965-57-1
methyl N-{2-[(E)-2-(phenylsulfonyl)vinyl]phenyl}-N-[(2-pyridyl)sulfonyl]glycinate

Guidance literature:: Multi-step reaction with 4 steps

1: sodium hypochlorite; sulfuric acid / water / 0.25 h / 0 °C

2: pyridine / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

3: potassium carbonate / acetonitrile / 20 °C / Inert atmosphere

4: palladium diacetate; 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate / 1,1-dichloroethane / 18 h / 110 °C / Inert atmosphere

With pyridine; sodium hypochlorite; sulfuric acid; palladium diacetate; potassium carbonate; 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate; In tetrahydrofuran; 1,1-dichloroethane; water; acetonitrile; 4: Fujiwara-Moritani reaction;
DOI:10.1002/anie.201105611

Reference yield:

: 103863-00-9
N-Phenylpyridine-2-sulfonamide

: 1352965-57-1
methyl N-{2-[(E)-2-(phenylsulfonyl)vinyl]phenyl}-N-[(2-pyridyl)sulfonyl]glycinate

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / acetonitrile / 20 °C / Inert atmosphere

2: palladium diacetate; 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate / 1,1-dichloroethane / 18 h / 110 °C / Inert atmosphere

With palladium diacetate; potassium carbonate; 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate; In 1,1-dichloroethane; acetonitrile; 2: Fujiwara-Moritani reaction;
DOI:10.1002/anie.201105611