[bis(triphenylphosphoranylidene)ammonium][(nitrosyl)Fe(1,2-benzenedithiolato)2]

Base Information

• Chemical Name: [bis(triphenylphosphoranylidene)ammonium][(nitrosyl)Fe(1,2-benzenedithiolato)2]
• CAS No.: 608130-20-7
• Molecular Formula: C₁₂H₈FeNOS₄*C₃₆H₃₀NP₂
• Molecular Weight: 904.901
• Mol file: 608130-20-7.mol

Synonyms:[bis(triphenylphosphoranylidene)ammonium][(nitrosyl)Fe(1,2-benzenedithiolato)2]

Chemical Property of [bis(triphenylphosphoranylidene)ammonium][(nitrosyl)Fe(1,2-benzenedithiolato)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [bis(triphenylphosphoranylidene)ammonium][(nitrosyl)Fe(1,2-benzenedithiolato)2]

There total 6 articles about [bis(triphenylphosphoranylidene)ammonium][(nitrosyl)Fe(1,2-benzenedithiolato)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(S5)] (748781-52-4) + [PPN][(C4H8O)Fe(S,S-C6H4)2] (608130-18-3) → (PPN)2{Fe2S12} + [bis(triphenylphosphoranylidene)ammonium][(nitrosyl)Fe(1,2-benzenedithiolato)2] (608130-20-7)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); under N2 atm. (PPN)(S5Fe(NO)2) and (PPN)((C4H8O)Fe(S,S-C6H4)2) in THF atroom temp. were irradiated with UV lamp (352 nm) for 1 h and stirred in the dark for 30 min; (PPN)2(S5Fe(μ-S)2FeS5) was filtered and recrystd. from CH2Cl2-Et2O-hexane, filtrate was concd. in vacuo, hexane-Et2O was added - (PPN)((NO)Fe(S,S-C6H4)2);

DOI:10.1021/ic0494915

Reference yield: 84.0%

[bis(triphenylphosphoranylidene)ammonium]2[(nitrosyl)Fe(1,2-benzenedithiolato)2] + oxygen (80937-33-3) → [bis(triphenylphosphoranylidene)ammonium][(nitrosyl)Fe(1,2-benzenedithiolato)2] (608130-20-7) + [bis(triphenylphosphoranylidene)ammonium]2[Fe(1,2-benzenedithiolato)2]2

Guidance literature:

In acetonitrile; byproducts: (Ph3PNPPh3)NO3; Irradiation (UV/VIS); under N2; MeCN soln. of Fe complex purged with O2 (14 psi) at 293 K; stirred at room temp. for 3 h; concd.; Et2O added; stored for 20 min; solvent removed by cannula; soliddried under vac.; extd. (THF-Et2O); recrystd. from THF-hexane diffusion ; MeCN-THF added to residue, crystd. by Et2O diffusion (room temp., 1 wk); detd. by IR and UV-vis spectra;

DOI:10.1021/ic050108l

Reference yield: 40.0%

[bis(triphenylphosphoranylidene)ammonium][Se5Fe(NO)2] + [bis(triphenylphosphoranylidene)ammonium]2[Fe(S2C6H4)2] → [bis(triphenylphosphoranylidene)ammonium][(NO)Fe(S2C6H4)2] (608130-20-7)

Guidance literature:

In tetrahydrofuran; byproducts: Se; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of iron complexes in THF at room temp. for 6h, stirring for 2 h in the dark; filtration, concn., addn. of hexane/Et2O;

DOI:10.1016/j.ica.2006.02.035

upstream raw materials:

[PPN][(C₄H₈O)Fe(S,S-C₆H₄)2]

nitrogen(II) oxide

[bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(S₅)]

oxygen