Cyclobutanecarboxaldehyde, 3-acetyl-2,2-dimethyl-, (1R,3S)- (9CI)

Base Information

Chemical Name:Cyclobutanecarboxaldehyde, 3-acetyl-2,2-dimethyl-, (1R,3S)- (9CI)
CAS No.:177316-72-2
Molecular Formula:C₉H₁₄O₂
Molecular Weight:154.209
Hs Code.:
Mol file:177316-72-2.mol

Synonyms:Cyclobutanecarboxaldehyde,3-acetyl-2,2-dimethyl-, (1R-cis)-; (1R,3S)-3-Acetyl-2,2-dimethylcyclobutanecarboxaldehyde

Suppliers and Price of Cyclobutanecarboxaldehyde, 3-acetyl-2,2-dimethyl-, (1R,3S)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Cyclobutanecarboxaldehyde, 3-acetyl-2,2-dimethyl-, (1R,3S)- (9CI)

Chemical Property:

PSA：0.00000
LogP:0.00000

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Cyclobutanecarboxaldehyde, 3-acetyl-2,2-dimethyl-, (1R,3S)- (9CI)

There total 8 articles about Cyclobutanecarboxaldehyde, 3-acetyl-2,2-dimethyl-, (1R,3S)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 7785-70-8,25766-18-1
(+)-α-pinene

: 132478-08-1,177316-72-2
cis-pinononic aldehyde

: C₈H₁₂O₂

Guidance literature:: (+)-α-pinene; With ferrous(II) sulfate heptahydrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; ozone; In methanol; water; at -78 - 20 ℃; for 0.0833333h;

With magnesium bis(monoperoxyphthalate)hexahydrate; In methanol; water; at 0 ℃; for 2h; Overall yield = 67 percent; Overall yield = 190 mg;
DOI:10.1002/anie.201913201

Reference yield:

: 71628-89-2
(1S,3S)-3-acetyl-2,2-dimethylcyclobutaneacetaldehyde1,6-cyclodecanedione

: 132478-08-1,177316-72-2
cis-pinononic aldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: (C₂H₅)3N, 4-dimethylaminopyridine / 1) 0 deg C, 1 h, 2) 25 deg C, 24 h

2: 1) O₃, 2) (CH₃)2S / 1) CH₂Cl₂, -78 deg C, 3 h, 2) 25 deg C, overnight

With dmap; dimethylsulfide; ozone; triethylamine;
DOI:10.1080/00397919608003550