Tert-butyl-dimethyl-propa-1,2-dienylsilane

Base Information

Chemical Name:Tert-butyl-dimethyl-propa-1,2-dienylsilane
CAS No.:176545-76-9
Molecular Formula:C9H18 Si
Molecular Weight:154.327
Hs Code.:
DSSTox Substance ID:DTXSID00402525
Nikkaji Number:J746.657I
Mol file:176545-76-9.mol

Synonyms:tert-butyl-dimethyl-propa-1,2-dienylsilane;(tert-Butyldimethylsilyl)allene;176545-76-9;DTXSID00402525;tert-Butyl(dimethyl)propadienylsilane;1-(tert-Butyldimethylsilyl)propadiene

Suppliers and Price of Tert-butyl-dimethyl-propa-1,2-dienylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Tert-butyl-dimethyl-propa-1,2-dienylsilane

Chemical Property:

PSA：0.00000
LogP:3.37520
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:154.117777109
Heavy Atom Count:10
Complexity:154

Purity/Quality:: 98%Min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)C=C=C

Technology Process of Tert-butyl-dimethyl-propa-1,2-dienylsilane

There total 2 articles about Tert-butyl-dimethyl-propa-1,2-dienylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: C₁₃H₂₅BNO₂Si^(1-)*H⁽¹⁺⁾

: 176545-76-9
tertbutyldimethylsilylpropa-1,2-diene

Guidance literature:: C₁₃H₂₅BNO₂Si^(1-)*H⁽¹⁺⁾; With trifluoroacetic acid; In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere;

With water; In dichloromethane; at 20 ℃; for 1h; regioselective reaction; Inert atmosphere;
DOI:10.1021/ol9022529

Reference yield: 70.0%

: 120789-51-7
3-tert-butyldimethylsilylpropargyl alcohol

: 176545-76-9
tertbutyldimethylsilylpropa-1,2-diene

Guidance literature:: 3-tert-butyldimethylsilylpropargyl alcohol; With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at -15 ℃; for 0.116667h; Inert atmosphere;

With 2-nitrobenzenesulfonyl hydrazide; In tetrahydrofuran; at -15 - 23 ℃; for 5.75h; Inert atmosphere;
DOI:10.15227/orgsyn.076.0178

Reference yield: 82.0%

: 19562-37-9
3-(4-methylphenyl)benzo-1,2,3-triazin-4(3H)-one

: 176545-76-9
tertbutyldimethylsilylpropa-1,2-diene

: 1204307-38-9
C₂₃H₂₉NOSi

Guidance literature:: With bis(1,5-cyclooctadiene)nickel⁽⁰⁾; trimethylphosphane; In tetrahydrofuran; at 60 ℃; Inert atmosphere;
DOI:10.1021/ja909603j