O-Benzyl-N-((3aR,4aR,7S,7aS,7bR)-2,2-dimethyl-hexahydro-cyclopenta[4,5]furo[2,3-d][1,3]dioxol-7-yl)-hydroxylamine

Base Information

Chemical Name:O-Benzyl-N-((3aR,4aR,7S,7aS,7bR)-2,2-dimethyl-hexahydro-cyclopenta[4,5]furo[2,3-d][1,3]dioxol-7-yl)-hydroxylamine
CAS No.:144733-70-0
Molecular Formula:C₁₇H₂₃NO₄
Molecular Weight:305.374
Hs Code.:

Synonyms:O-Benzyl-N-((3aR,4aR,7S,7aS,7bR)-2,2-dimethyl-hexahydro-cyclopenta[4,5]furo[2,3-d][1,3]dioxol-7-yl)-hydroxylamine

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Chemical Property of O-Benzyl-N-((3aR,4aR,7S,7aS,7bR)-2,2-dimethyl-hexahydro-cyclopenta[4,5]furo[2,3-d][1,3]dioxol-7-yl)-hydroxylamine

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Technology Process of O-Benzyl-N-((3aR,4aR,7S,7aS,7bR)-2,2-dimethyl-hexahydro-cyclopenta[4,5]furo[2,3-d][1,3]dioxol-7-yl)-hydroxylamine

There total 11 articles about O-Benzyl-N-((3aR,4aR,7S,7aS,7bR)-2,2-dimethyl-hexahydro-cyclopenta[4,5]furo[2,3-d][1,3]dioxol-7-yl)-hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 144677-74-7
(E)-5-((3aR,5R,6S,6aR)-2,2-Dimethyl-6-methylsulfanylthiocarboxyoxy-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-methyl-pent-2-enoic acid ethyl ester

: 144733-70-0
O-Benzyl-N-((3aR,4aR,7S,7aS,7bR)-2,2-dimethyl-hexahydro-cyclopenta[4,5]furo[2,3-d][1,3]dioxol-7-yl)-hydroxylamine

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene;
DOI:10.1016/S0040-4020(01)81837-8

Reference yield: 45.0%

: 151426-58-3
Imidazole-1-carbothioic acid O-[(3aR,5R,6S,6aR)-5-(3-benzyloxyimino-propyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl] ester

: 144733-70-0
O-Benzyl-N-((3aR,4aR,7S,7aS,7bR)-2,2-dimethyl-hexahydro-cyclopenta[4,5]furo[2,3-d][1,3]dioxol-7-yl)-hydroxylamine

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene;
DOI:10.1016/S0040-4020(01)81837-8

Reference yield:

: 136839-01-5
ethyl 5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-heptofuranuronate

: 144733-70-0
O-Benzyl-N-((3aR,4aR,7S,7aS,7bR)-2,2-dimethyl-hexahydro-cyclopenta[4,5]furo[2,3-d][1,3]dioxol-7-yl)-hydroxylamine

Guidance literature:: Multi-step reaction with 4 steps

1: 98 percent / DIBALH / toluene; hexane / 0.5 h / -78 °C

2: 69 percent / pyridine / H₂O; CH₂Cl₂ / 0.83 h / Heating

3: 95 percent / CH₂Cl₂ / 2 h / Heating

4: 45 percent / tributyltin hydride, AIBN / toluene

With pyridine; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; diisobutylaluminium hydride; In hexane; dichloromethane; water; toluene;
DOI:10.1016/S0040-4020(01)81837-8