(1S,5R,7S)-1,5,7-Tris-benzyloxymethyl-2,4-dioxo-3-aza-bicyclo[3.3.1]nonane-7-carbonyl chloride

Base Information

Chemical Name:(1S,5R,7S)-1,5,7-Tris-benzyloxymethyl-2,4-dioxo-3-aza-bicyclo[3.3.1]nonane-7-carbonyl chloride
CAS No.:146651-53-8
Molecular Formula:C₃₃H₃₄ClNO₆
Molecular Weight:576.089
Hs Code.:

Synonyms:(1S,5R,7S)-1,5,7-Tris-benzyloxymethyl-2,4-dioxo-3-aza-bicyclo[3.3.1]nonane-7-carbonyl chloride

Suppliers and Price of (1S,5R,7S)-1,5,7-Tris-benzyloxymethyl-2,4-dioxo-3-aza-bicyclo[3.3.1]nonane-7-carbonyl chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1S,5R,7S)-1,5,7-Tris-benzyloxymethyl-2,4-dioxo-3-aza-bicyclo[3.3.1]nonane-7-carbonyl chloride

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1S,5R,7S)-1,5,7-Tris-benzyloxymethyl-2,4-dioxo-3-aza-bicyclo[3.3.1]nonane-7-carbonyl chloride

There total 7 articles about (1S,5R,7S)-1,5,7-Tris-benzyloxymethyl-2,4-dioxo-3-aza-bicyclo[3.3.1]nonane-7-carbonyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 146651-52-7
(1S,5R,7S)-1,5,7-Tris-benzyloxymethyl-2,4-dioxo-3-aza-bicyclo[3.3.1]nonane-7-carboxylic acid

: 146651-53-8
(1S,5R,7S)-1,5,7-Tris-benzyloxymethyl-2,4-dioxo-3-aza-bicyclo[3.3.1]nonane-7-carbonyl chloride

Guidance literature:: With thionyl chloride; for 2h; Heating;
DOI:10.1021/ja00087a013

Reference yield:

: 52831-11-5
trimethyl cyclohexane-1,3,5-tricarboxylate

: 146651-53-8
(1S,5R,7S)-1,5,7-Tris-benzyloxymethyl-2,4-dioxo-3-aza-bicyclo[3.3.1]nonane-7-carbonyl chloride

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) LDA / 1.) toluene, cyclohexane, a) -78 deg C, 30 min, b) 0 deg C, 30 min, 2.) toluene, cyclohexane, from -40 deg C to 25 deg C, 5 h 15 min

2: 83 percent / KOH / ethanol / 4 h / Heating

3: xylene / Heating

4: 64 percent / NH₄OH / tetrahydrofuran / 2 h / Heating

5: 100 percent / SOCl₂ / 2 h / Heating

With potassium hydroxide; ammonium hydroxide; thionyl chloride; lithium diisopropyl amide; In tetrahydrofuran; ethanol; xylene;
DOI:10.1021/ja00087a013

Reference yield:

: 146667-27-8
Kemp's anhydride acid

: 146651-53-8
(1S,5R,7S)-1,5,7-Tris-benzyloxymethyl-2,4-dioxo-3-aza-bicyclo[3.3.1]nonane-7-carbonyl chloride

Guidance literature:: Multi-step reaction with 2 steps

1: 64 percent / NH₄OH / tetrahydrofuran / 2 h / Heating

2: 100 percent / SOCl₂ / 2 h / Heating

With ammonium hydroxide; thionyl chloride; In tetrahydrofuran;
DOI:10.1021/ja00087a013