(mesitylene)(phenylisonitrile)osmium(II) dichloride

Base Information

Chemical Name:(mesitylene)(phenylisonitrile)osmium(II) dichloride
CAS No.:136033-83-5
Molecular Formula:C₁₆H₁₇Cl₂NOs
Molecular Weight:484.424
Hs Code.:

Synonyms:(mesitylene)(phenylisonitrile)osmium(II) dichloride

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Chemical Property of (mesitylene)(phenylisonitrile)osmium(II) dichloride

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Technology Process of (mesitylene)(phenylisonitrile)osmium(II) dichloride

There total 1 articles about (mesitylene)(phenylisonitrile)osmium(II) dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 126724-08-1
(mesitylene)osmium dichloride

: 1197040-29-1,931-54-4
phenyl isocyanate

: 136033-83-5
(mesitylene)(phenylisonitrile)osmium(II) dichloride

Guidance literature:: In dichloromethane; under Ar; a suspn. of ((mes)OsCl2) is treated with the isocyanide; mixt. stirred for 3 h at 40°C; soln. filtered; residue washed (CH2Cl2); filtrate concd.; addn of ether; ppt. filtered, washed (ether/hexane), dried (vac.); elem. anal.;
DOI:10.1021/om00055a053

Reference yield: 69.0%

: 136033-83-5
(mesitylene)(phenylisonitrile)osmium(II) dichloride

: OsH((CH₃)3C₆H₃)(N(C₆H₅)C(C₆H₅)(C₆H₄))

: ((mesitylene)phenyl(phenylisonitrilo))osmium(II) bromide

Guidance literature:: With C₆H₅MgBr; In diethyl ether; benzene; (Ar); to a suspn. of Os-compd. in benzene a soln. of C6H5MgBr in ether is added, mixt. is stirred for 30 min; solvent is removed by addn. of Al2O3 under vac., residue is extd. with benzene, soln. is chromd. (Al2O3; eluents: CH2Cl2 and benzene), fractions are dried to dryness, residue is recrystd. from hexane (25 to -78°C); elem. anal.;
DOI:10.1016/0022-328X(94)88074-3

Reference yield: 59.0%

: 136033-83-5
(mesitylene)(phenylisonitrile)osmium(II) dichloride

: 16002-63-4
phenylmagnesium iodide

: (mesitylene)phenyl(phenylisonitrile)osmium(II) iodide

: 156823-34-6
(mesitylene)(phenylisonitrile)osmium(II) diiodide

Guidance literature:: In diethyl ether; benzene; (Ar); to a suspn. of Os-compd. in benzene a soln. of PhMgI in ether is added, mixt. is stirred for 30 min at room temp.; solvent is evapd. in vac., residue is extd. with benzene, soln. is chromd. (Al2O3; eluent: benzene); elem. anal.;
DOI:10.1016/0022-328X(94)88074-3