Tert-butyl (3-iodo-4-oxocyclohex-2-en-1-yl)carbamate

Base Information

Chemical Name:Tert-butyl (3-iodo-4-oxocyclohex-2-en-1-yl)carbamate
CAS No.:205877-96-9
Molecular Formula:C₁₁H₁₆INO₃
Molecular Weight:337.157
Hs Code.:
European Community (EC) Number:963-760-0

Synonyms:205877-96-9;Tert-butyl (3-iodo-4-oxocyclohex-2-en-1-yl)carbamate;tert-butyl N-(3-iodo-4-oxocyclohex-2-en-1-yl)carbamate;MFCD32197076;AKOS037646490;AS-69162;W18536;EN300-1159721;t-Butyl (3-iodo-4-oxocyclohex-2-en-1-yl)carbamate;Tert-butyl(3-iodo-4-oxocyclohex-2-en-1-yl)carbamate

Suppliers and Price of Tert-butyl (3-iodo-4-oxocyclohex-2-en-1-yl)carbamate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Tert-butyl (3-iodo-4-oxocyclohex-2-en-1-yl)carbamate

Chemical Property:

XLogP3:1.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:337.01749
Heavy Atom Count:16
Complexity:331

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)OC(=O)NC1CCC(=O)C(=C1)I

Technology Process of Tert-butyl (3-iodo-4-oxocyclohex-2-en-1-yl)carbamate

There total 4 articles about Tert-butyl (3-iodo-4-oxocyclohex-2-en-1-yl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 205877-92-5,455330-42-4
(4-Oxo-cyclohex-2-enyl)-carbamic acid tert-butyl ester

: 205877-96-9
(3-Iodo-4-oxo-cyclohex-2-enyl)-carbamic acid tert-butyl ester

Guidance literature:: With pyridine; iodine;
DOI:10.1016/S0040-4039(98)00187-7

Reference yield:

: 36016-38-3
tert-Butyl N-hydroxycarbamate

: 205877-96-9
(3-Iodo-4-oxo-cyclohex-2-enyl)-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 89 percent / (n-Bu)4NIO₄ / CH₂Cl₂; methanol / -25 °C

2: 91 percent / Mo(CO)6 / acetonitrile; H₂O

3: 88 percent / MnO₂

4: 88 percent / I₂, pyridine

With pyridine; manganese(IV) oxide; hexacarbonyl molybdenum; iodine; tetrabutylammonium periodite; In methanol; dichloromethane; water; acetonitrile;
DOI:10.1016/S0040-4039(98)00187-7

Reference yield:

: 110590-29-9
tert-butyl 2-oxa-3-azabicyclo[2.2.2]oct-5-ene-3-carboxylate

: 205877-96-9
(3-Iodo-4-oxo-cyclohex-2-enyl)-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / Mo(CO)6 / acetonitrile; H₂O

2: 88 percent / MnO₂

3: 88 percent / I₂, pyridine

With pyridine; manganese(IV) oxide; hexacarbonyl molybdenum; iodine; In water; acetonitrile;
DOI:10.1016/S0040-4039(98)00187-7