tert-butyl-[4-iodo-1-(4-methoxy-benzyloxymethyl)-pent-3-enyloxy]-dimethyl-silane

Base Information

Chemical Name:tert-butyl-[4-iodo-1-(4-methoxy-benzyloxymethyl)-pent-3-enyloxy]-dimethyl-silane
CAS No.:444809-50-1
Molecular Formula:C₂₀H₃₃IO₃Si
Molecular Weight:476.47
Hs Code.:

<i>tert</i>-butyl-[4-iodo-1-(4-methoxy-benzyloxymethyl)-pent-3-enyloxy]-dimethyl-silane

Synonyms:tert-butyl-[4-iodo-1-(4-methoxy-benzyloxymethyl)-pent-3-enyloxy]-dimethyl-silane

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Chemical Property of tert-butyl-[4-iodo-1-(4-methoxy-benzyloxymethyl)-pent-3-enyloxy]-dimethyl-silane

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Technology Process of tert-butyl-[4-iodo-1-(4-methoxy-benzyloxymethyl)-pent-3-enyloxy]-dimethyl-silane

There total 4 articles about tert-butyl-[4-iodo-1-(4-methoxy-benzyloxymethyl)-pent-3-enyloxy]-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 444809-50-1
tert-butyl-[4-iodo-1-(4-methoxy-benzyloxymethyl)-pent-3-enyloxy]-dimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: K₂CO₃ / methanol

1.2: C₃H₄N₂

2.1: BuLi

3.1: Cp₂ZrCl₂; DIBAL / tetrahydrofuran; benzene / 50 °C

3.2: 68 percent / NIS

With n-butyllithium; zirconocene dichloride; diisobutylaluminium hydride; potassium carbonate; In tetrahydrofuran; methanol; benzene;
DOI:10.1016/S0040-4039(02)00403-3

Reference yield:

: 824-94-2
p-methoxybenzyl chloride

: 444809-50-1
tert-butyl-[4-iodo-1-(4-methoxy-benzyloxymethyl)-pent-3-enyloxy]-dimethyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1.1: NaI; TBAI; NaH / dimethylformamide

1.2: BF₃*OEt₂

2.1: K₂CO₃ / methanol

2.2: C₃H₄N₂

3.1: BuLi

4.1: Cp₂ZrCl₂; DIBAL / tetrahydrofuran; benzene / 50 °C

4.2: 68 percent / NIS

With n-butyllithium; zirconocene dichloride; tetra-(n-butyl)ammonium iodide; sodium hydride; diisobutylaluminium hydride; potassium carbonate; sodium iodide; In tetrahydrofuran; methanol; N,N-dimethyl-formamide; benzene;
DOI:10.1016/S0040-4039(02)00403-3

Reference yield:

: 444809-41-0
1-(para-methoxybenzyloxy)-5-trimethylsilyl-4-pentyn-2-ol

: 444809-50-1
tert-butyl-[4-iodo-1-(4-methoxy-benzyloxymethyl)-pent-3-enyloxy]-dimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: K₂CO₃ / methanol

1.2: C₃H₄N₂

2.1: BuLi

3.1: Cp₂ZrCl₂; DIBAL / tetrahydrofuran; benzene / 50 °C

3.2: 68 percent / NIS

With n-butyllithium; zirconocene dichloride; diisobutylaluminium hydride; potassium carbonate; In tetrahydrofuran; methanol; benzene;
DOI:10.1016/S0040-4039(02)00403-3