C₃₅H₄₂O₁₁

Base Information

• Chemical Name: C₃₅H₄₂O₁₁
• CAS No.: 1338782-78-7
• Molecular Formula: C₃₅H₄₂O₁₁
• Molecular Weight: 638.712
• Mol file: 1338782-78-7.mol

Synonyms:C₃₅H₄₂O₁₁

Chemical Property of C₃₅H₄₂O₁₁

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₅H₄₂O₁₁

There total 7 articles about C₃₅H₄₂O₁₁ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

C63H58O15 (1338782-77-6) → C35H42O11 (1338782-78-7)

Guidance literature:

With sodium methylate; In methanol; at 20 ℃; for 7h; Inert atmosphere;

DOI:10.1039/c1cc14025f

Reference yield:

(Z)-methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-gluco-hex-5-enopyranoside (137793-90-9) → C35H42O11 (1338782-78-7)

Guidance literature:

Multi-step reaction with 4 steps

1: diethylzinc / hexane; 1,2-dichloro-ethane / 48 h / 50 °C / Molecular sieve

2: water; potassium carbonate / methanol / 1 h / 20 °C

3: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 1 h / 0 °C / Inert atmosphere

4: sodium methylate / methanol / 7 h / 20 °C / Inert atmosphere

With trimethylsilyl trifluoromethanesulfonate; water; diethylzinc; sodium methylate; potassium carbonate; In methanol; hexane; dichloromethane; 1,2-dichloro-ethane; 1: Simmons-Smith-Furukawa reaction;

DOI:10.1039/c1cc14025f

Reference yield:

2,3,4,6-tetra-O-benzoyl-D-glucopyranosyl trichloroacetimidate (149707-75-5) → C35H42O11 (1338782-78-7)

Guidance literature:

Multi-step reaction with 2 steps

1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 1 h / 0 °C / Inert atmosphere

2: sodium methylate / methanol / 7 h / 20 °C / Inert atmosphere

With trimethylsilyl trifluoromethanesulfonate; sodium methylate; In methanol; dichloromethane;

DOI:10.1039/c1cc14025f

upstream raw materials:

C₃₁H₃₄O₇

C₂₉H₃₂O₆

C₆₃H₅₈O₁₅

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside