(1S,3R,6R,9S)-8-methoxy-3-(4'-methoxyphenyl)-8-methyl-10-methylene-2,4,7-trioxabicyclo[4.4.0]decane

Base Information

Chemical Name:(1S,3R,6R,9S)-8-methoxy-3-(4'-methoxyphenyl)-8-methyl-10-methylene-2,4,7-trioxabicyclo[4.4.0]decane
CAS No.:391611-31-7
Molecular Formula:C₁₇H₂₂O₅
Molecular Weight:306.359
Hs Code.:

Synonyms:(1S,3R,6R,9S)-8-methoxy-3-(4'-methoxyphenyl)-8-methyl-10-methylene-2,4,7-trioxabicyclo[4.4.0]decane

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Chemical Property of (1S,3R,6R,9S)-8-methoxy-3-(4'-methoxyphenyl)-8-methyl-10-methylene-2,4,7-trioxabicyclo[4.4.0]decane

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Technology Process of (1S,3R,6R,9S)-8-methoxy-3-(4'-methoxyphenyl)-8-methyl-10-methylene-2,4,7-trioxabicyclo[4.4.0]decane

There total 10 articles about (1S,3R,6R,9S)-8-methoxy-3-(4'-methoxyphenyl)-8-methyl-10-methylene-2,4,7-trioxabicyclo[4.4.0]decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 878673-34-8
(1S,4S,6R,9R)-4-methoxy-9-(4'-methoxyphenyl)-4-methyl-5,8,10-trioxabicyclo[4.4.0]decan-2-one

: 391611-31-7
(1S,3R,6R,9S)-8-methoxy-3-(4'-methoxyphenyl)-8-methyl-10-methylene-2,4,7-trioxabicyclo[4.4.0]decane

Guidance literature:: With pyridine; In tetrahydrofuran; at -20 ℃;
DOI:10.1016/S0040-4039(01)01763-4

Reference yield:

: 2186-92-7
p-Anisaldehyde dimethyl acetal

: 391611-31-7
(1S,3R,6R,9S)-8-methoxy-3-(4'-methoxyphenyl)-8-methyl-10-methylene-2,4,7-trioxabicyclo[4.4.0]decane

Guidance literature:: Multi-step reaction with 3 steps

1: 84 percent / p-toluenesulfonic acid / dimethylformamide / 0.67 h / 60 °C

2: 95 percent / pyridine; Dess-Martin periodinane / CH₂Cl₂ / 18 h / 20 °C

3: 94 percent / pyridine / tetrahydrofuran; toluene / 0.33 h / -20 °C

With pyridine; Dess-Martin periodane; toluene-4-sulfonic acid; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1016/j.tet.2005.11.031

Reference yield:

: 878673-33-7
(1S,2R,4S,6R,9R)-4-methoxy-9-(4'-methoxyphenyl)-4-methyl-5,8,10-trioxabicyclo[4.4.0]decan-2-ol

: 391611-31-7
(1S,3R,6R,9S)-8-methoxy-3-(4'-methoxyphenyl)-8-methyl-10-methylene-2,4,7-trioxabicyclo[4.4.0]decane

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / pyridine; Dess-Martin periodinane / CH₂Cl₂ / 18 h / 20 °C

2: 94 percent / pyridine / tetrahydrofuran; toluene / 0.33 h / -20 °C

With pyridine; Dess-Martin periodane; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1016/j.tet.2005.11.031