[(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn₃(C₆F₅)2]

Base Information

• Chemical Name: [(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn₃(C₆F₅)2]
• CAS No.: 1008098-68-7
• Molecular Formula: C₃₆H₇₂F₁₀O₄Si₁₂Zn₃
• Molecular Weight: 1292.15
• Mol file: 1008098-68-7.mol

Synonyms:[(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn₃(C₆F₅)2]

Chemical Property of [(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn₃(C₆F₅)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn₃(C₆F₅)2]

There total 3 articles about [(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn₃(C₆F₅)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

[(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn3Me2] (1008098-66-5) + tris(pentafluorophenyl)borate (1109-15-5) → [(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn3(C6F5)2] (1008098-68-7)

Guidance literature:

In pentane; under Ar, schlenk techniques; B compd. and Zn compd. (1:1) dissolved in n-pentane at -20°C, stirred for 2 h at room temp.; crystd. on cooling, elem. anal.;

DOI:10.1002/ejic.200600957

Reference yield:

[(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn3Me2] (1008098-66-5) + tris(pentafluorophenyl)borate (1109-15-5) → dimethylpentafluorophenylborane (363596-54-7) + trimethylborane (593-90-8) + [(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn3(C6F5)2] (1008098-68-7) + methylbis(pentafluorophenyl)borane (170151-48-1)

Guidance literature:

In benzene-d6; soln. of B compd. and Zn compd. (1:1) for 2 h at room temp.; NMR;

DOI:10.1002/ejic.200600957

Reference yield:

2,3-dihydroxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane (934166-23-1) → [(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn3(C6F5)2] (1008098-68-7)

Guidance literature:

Multi-step reaction with 2 steps

1: n-heptane; pentane

2: pentane

In n-heptane; pentane;

DOI:10.1002/ejic.200600957

upstream raw materials:

[(2,3-dihydoxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane(-2H))2Zn₃Me₂]

tris(pentafluorophenyl)borate

2,3-dihydroxy-1,1,1,4,4,4-hexamethyl-2,3-bis(trimethylsilyl)tetrasilane