(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride

Base Information

• Chemical Name: (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride
• CAS No.: 415701-46-1
• Molecular Formula: C₃₅H₅₃ClFeN₂
• Molecular Weight: 593.119
• Mol file: 415701-46-1.mol

Synonyms:(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride

Chemical Property of (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride

There total 3 articles about (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

iron(dichloride)*1.5(tetrahydrofuran) + potassium 1,5-bis(2,6-diisopropylphenyl)-2,4-di-tert-butyl-1,5-diazapenta-1,3-dienate + water (7732-18-5) → N,N′-bis(2,6-diisopropylphenyl)-2,2,6,6-tetramethylheptane-3,5-diimine + (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride (415701-46-1)

Guidance literature:

In toluene; byproducts: KCl; under N2; mixt. of K salt of ligand, FeCl2*1.5THF and toluene heated at 100°C (oil bath) for 18 h; cooled; ligand obtained from trace amt. of H2O; filtered through Celite; concd.; warmed to dissolve small amt. of solid;crystd. at -40°C overnight; supernatant decanted; solid washed w ith pentane;

DOI:10.1021/ic802440h

Reference yield: 94.0%

iron(dichloride)*1.5(tetrahydrofuran) + [Li(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)(THF)] → (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride (415701-46-1)

Guidance literature:

In toluene; (N2); heating a mixt. of iron salt with lithium compd. in toluene at 100°C for 24 h; evapn., extn. with hot Et2O (Soxhlet) for 1-2 d, concn., filtration, further crystn. from filtrate at -35°C;

DOI:10.1021/om020571v

Reference yield:

(CH(C(t-Bu)NC6H3(i-Pr)2)2)FeCl(acetonitrile) (923951-88-6) → (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride (415701-46-1)

Guidance literature:

In neat (no solvent); standing for 2 h at room temp.;

DOI:10.1021/ic0609148

upstream raw materials:

(CH(C(t-Bu)NC₆H₃(i-Pr)2)2)FeCl(acetonitrile)

water

Downstream raw materials:

((((CH₃)2CH)2C₆H₃)2((CH₃)3C)2C₃HN₂Fe⁽¹⁵⁾N)2

(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenyl)imidohept-4-yl)FeEt

(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenyl)imidohept-4-yl)Fe(i)Pr

(((CH₃)2CH)2C₆H₃NC(C(CH₃)3)CHC(C(CH₃)3)NC₆H₃(CH(CH₃)2)2)Fe(OC(CH₃)3)