[(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(μ-H)]2

Base Information

• Chemical Name: [(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(μ-H)]2
• CAS No.: 647823-71-0
• Molecular Formula: C₇₀H₁₀₈Fe₂N₄
• Molecular Weight: 1117.35
• Mol file: 647823-71-0.mol

Synonyms:[(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(μ-H)]2

Chemical Property of [(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(μ-H)]2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(μ-H)]2

There total 4 articles about [(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(μ-H)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

triethylsilane (617-86-7) + (((2,6-di(isopropyl)phenyl)N)2C3H-t-Bu2 iron(II) fluoride (854669-27-5) → [(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(μ-H)]2 (647823-71-0)

Guidance literature:

In toluene; byproducts: (C2H5)3SiF; (N2); Et3SiH was added to slurry of iron complex in toluene, sealed, stirred at 100°C overnight, cooled to room temp.; evapd. in vac., dissolved in Et2O, filtered through celite, concd., crystd. at -45°C;

DOI:10.1016/j.jorganchem.2009.04.005

Reference yield: 78.0%

(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride (415701-46-1) + potassium triethylborohydride → [(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(μ-H)]2 (647823-71-0)

Guidance literature:

In not given;

DOI:10.1021/ja038152s

Reference yield: 58.0%

(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride (415701-46-1) + hydrogen (1333-74-0) → [(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl)Fe(μ-H)]2 (647823-71-0)

Guidance literature:

With KC₈; In diethyl ether; byproducts: graphite; (N2); KC8 was added to soln. of iron complex in Et2O, sealed, stirred for 1 h, frozen, H2 (1 bar) was added, stirred overnight; filtered through celite, concd., crystd. at -45°C;

DOI:10.1016/j.jorganchem.2009.04.005

upstream raw materials:

(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)iron(II) chloride

hydrogen

triethylsilane

(((2,6-di(isopropyl)phenyl)N)2C₃H-t-Bu₂ iron(II) fluoride

Downstream raw materials:

Fe(CH(C₆H₃(CH(CH₃)2)2NC(C(CH₃)3))2)NC₆H₅⁽²⁾HNC₆H₅

(CH(C(C(CH3)3)NC6H3(CH(CH3)2)2)2)Fe(η2-iPrNCHNiPr)

(CH(C(C(CH3)3)NC6H3(CH(CH3)2)2)2)Fe(η2-NHNN(1-adamantyl))

(CH(C(CH₃)NC₆H₃(CH(CH₃)2)2)2)Fe(NCHtBu)