C₃₇H₄₆O₉S

Base Information

Chemical Name:C₃₇H₄₆O₉S
CAS No.:259258-01-0
Molecular Formula:C₃₇H₄₆O₉S
Molecular Weight:666.833
Hs Code.:

C<sub>37</sub>H<sub>46</sub>O<sub>9</sub>S

Synonyms:C₃₇H₄₆O₉S

Suppliers and Price of C₃₇H₄₆O₉S

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₃₇H₄₆O₉S

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₃₇H₄₆O₉S

There total 16 articles about C₃₇H₄₆O₉S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 98-59-9
p-toluenesulfonyl chloride

: 259258-00-9
C₃₀H₄₀O₇

: 259258-01-0
C₃₇H₄₆O₉S

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 0 ℃; for 2h;
DOI:10.1021/jo990988j

Reference yield:

: 100-39-0
benzyl bromide

: 259258-01-0
C₃₇H₄₆O₉S

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / sodium hydride / tetrahydrofuran; dimethylformamide; various solvent(s) / 0 - 50 °C

2: 77 percent / dimethyl sulfide; BF₃*Et₂O / CH₂Cl₂ / 0.33 h / 0 °C

3: 93 percent / 4-(dimethylamino)pyridine; triethylamine / CH₂Cl₂ / 2 h / 0 °C

With dmap; dimethylsulfide; boron trifluoride diethyl etherate; sodium hydride; triethylamine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; 1: Etherification / 2: Hydrolysis / 3: Tosylation;
DOI:10.1021/jo990988j

Reference yield:

: 157220-15-0
(2R,3S,4S,5S,6R,7S)-4-Benzyloxy-7-methoxymethoxymethyl-5-methyl-2-((S)-1-methyl-allyl)-6-triisopropylsilanyloxy-oxepan-3-ol

: 259258-01-0
C₃₇H₄₆O₉S

Guidance literature:: Multi-step reaction with 12 steps

1.1: 98 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / 2.5 h / 20 °C

2.1: 9-borabicyclo[3.3.1]nonane / tetrahydrofuran / 0 - 20 °C

2.2: 9.90 g / hydrogen peroxide; sodium hydroxide / tetrahydrofuran / 1.5 h / 20 °C

3.1: triethylamine; SO₃*pyridine / CH₂Cl₂; dimethylsulfoxide / 0.5 h / 0 °C

4.1: acetic acid / tetrahydrofuran; H₂O / 20 °C

5.1: 6.98 g / pyridinium dichromate; molecular sieves 4A / CH₂Cl₂ / 2 h / 20 °C

6.1: LiHMDS / tetrahydrofuran; hexane / 0.5 h / -78 °C

6.2: 92 percent / tetrahydrofuran; hexane / -78 - 0 °C

7.1: 79 percent / tetrahydrofuran; diethyl ether / 0.75 h / -78 °C

8.1: N,N'-bis(2,4,6-Me₃C₆H₂CH₂)-(S,S)-1,2-Ph₂-1,2-diaminoethane; osmium tetroxide / CH₂Cl₂ / 2 h / -90 °C

8.2: 85 percent / NaHSO₃ / tetrahydrofuran; H₂O / 2 h / Heating

9.1: 86 percent / camphorsulfonic acid / benzene / 36 h / 20 °C

10.1: 83 percent / sodium hydride / tetrahydrofuran; dimethylformamide; various solvent(s) / 0 - 50 °C

11.1: 77 percent / dimethyl sulfide; BF₃*Et₂O / CH₂Cl₂ / 0.33 h / 0 °C

12.1: 93 percent / 4-(dimethylamino)pyridine; triethylamine / CH₂Cl₂ / 2 h / 0 °C

With dmap; osmium(VIII) oxide; dipyridinium dichromate; pyridine-SO₃ complex; dimethylsulfide; 4 A molecular sieve; camphor-10-sulfonic acid; boron trifluoride diethyl etherate; pyridinium p-toluenesulfonate; sodium hydride; acetic acid; (1S,2S)-1,2-diphenyl-N¹,N²-bis(mesitylmethyl)ethane-1,2-diamine; triethylamine; 9-bora-bicyclo[3.3.1]nonane; lithium hexamethyldisilazane; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; benzene; 1.1: Addition / 2.1: hydroboration / 2.2: Oxidation / 3.1: Oxidation / 4.1: Hydrolysis / 5.1: Oxidation / 6.1: Metallation / 6.2: Methylation / 7.1: Addition / 8.1: Oxidation / 8.2: Ring cleavage / 9.1: Cyclization / 10.1: Etherification / 11.1: Hydrolysis / 12.1: Tosylation;
DOI:10.1021/jo990988j