cis-dihydrido-trans-bis(dimethylphenylphosphine)dicarbonyliron

Base Information

• Chemical Name: cis-dihydrido-trans-bis(dimethylphenylphosphine)dicarbonyliron
• CAS No.: 138606-24-3
• Molecular Formula: C₁₈H₂₄FeO₂P₂
• Molecular Weight: 390.182
• Mol file: 138606-24-3.mol

Synonyms:cis-dihydrido-trans-bis(dimethylphenylphosphine)dicarbonyliron

Chemical Property of cis-dihydrido-trans-bis(dimethylphenylphosphine)dicarbonyliron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-dihydrido-trans-bis(dimethylphenylphosphine)dicarbonyliron

There total 1 articles about cis-dihydrido-trans-bis(dimethylphenylphosphine)dicarbonyliron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

tetracarbonylhydridoferrate (17857-24-8) + Dimethyl(phenyl)phosphine (672-66-2) → cis-dihydrido-trans-bis(dimethylphenylphosphine)dicarbonyliron (138606-24-3)

Guidance literature:

With potassium hydrogencarbonate; In methanol; byproducts: CO; under Ar, using Schlenk techniques, soln. of KHFe(CO)4 in MeOH cooled to 5°C, addn. of phosphine at 5°C, Schlenk tube connected to a gas buret, stirred for 24 h at this temp., gas evolution occured; evapn. under reduced press. at 5°C, extrd. with cold hexane, filtered, washed with cold hexane, concd., addn. of CoCl2*6H2O, stirred for 0.5 h below 5°C, addn. of cold hexane, filtered (neutral alumina column), evapn. (reduced press.);

DOI:10.1021/om00039a045

Reference yield:

cis-dihydrido-trans-bis(dimethylphenylphosphine)dicarbonyliron (138606-24-3) + Dimethyl(phenyl)phosphine (672-66-2) → (CO)2Fe(P(CH3)2C6H5)3 (138606-25-4)

Guidance literature:

In ethanol; byproducts: H2; under Ar, using Schlenk techniques, react. in refluxing EtOH;

DOI:10.1021/om00039a045

Reference yield:

cis-dihydrido-trans-bis(dimethylphenylphosphine)dicarbonyliron (138606-24-3) + potassium hydride → hydridodicarbonylbis(dimethylphenylphosphine)iron (138606-28-7)

Guidance literature:

In tetrahydrofuran-d8; Sonication; under Ar, using Schlenk techniques, addn. of complex to a 4-fold excess of KH, sonicated at ca. 40°C (common ultrasonic cleaner) until no more gas evolution observed (1 h);

DOI:10.1021/om00039a045

upstream raw materials:

tetracarbonylhydridoferrate

Dimethyl(phenyl)phosphine

Downstream raw materials:

(CO)2Fe(P(CH₃)2C₆H₅)3

hydridodicarbonylbis(dimethylphenylphosphine)iron