tetracarbonylhydridoferrate

Base Information

• Chemical Name: tetracarbonylhydridoferrate
• CAS No.: 17857-24-8
• Molecular Formula: C₄HFeO₄*K
• Molecular Weight: 207.995
• Mol file: 17857-24-8.mol

Synonyms:tetracarbonylhydridoferrate

Chemical Property of tetracarbonylhydridoferrate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tetracarbonylhydridoferrate

There total 2 articles about tetracarbonylhydridoferrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

HFe2(1-)*8CO=HFe2(CO)8(1-) → iron pentacarbonyl (13463-40-6,37220-42-1) + potassium tetracarbonylhydridoferrate (17857-24-8)

Guidance literature:

With carbon monoxide; potassium carbonate; In methanol; not isolated, detected by IR;

DOI:10.1021/om00047a070

Reference yield:

K(1+)*HFe3(1-)*11CO=K[HFe3(CO)11] (87145-35-5) → iron pentacarbonyl (13463-40-6,37220-42-1) + potassium tetracarbonylhydridoferrate (17857-24-8)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; in presence of large excess of CO (1 atm) in THF at 25°C for 10 h;

DOI:10.1021/om00080a005

Reference yield: 98.0%

tetracarbonylhydridoferrate (17857-24-8) + bis(triphenylphosphine)iminium chloride (21050-13-5) → bis(triphenylphosphine)nitrogen(1+) tetracarbonylhydridoferrate (56791-54-9)

Guidance literature:

In methanol; water; addn. of PPNCl soln. (MeOH) to Fe complex soln. (MeOH/H2O) under Ar; rapid pptn.; addn. of MeOH; stirring at room temp., 0.5h; filtration; washing (H2O); drying (vac., 24h);

DOI:10.1021/om00045a015

upstream raw materials:

K⁽¹⁺⁾*HFe₃^(1-)*11CO=K[HFe₃(CO)11]

Downstream raw materials:

cis-dihydrido-trans-bis(triphenylphosphite)dicarbonyliron

[((C₂H₅)(C₆H₅)N)2PH]Fe(CO)4

[((C₆H₅)2N)2PH]Fe(CO)4

dipotassium tetracarbonylferrate