[6-Allyl-7-(1,1-dimethyl-allyloxy)-benzo[1,3]dioxol-5-yloxy]-tert-butyl-diphenyl-silane

Base Information

Chemical Name:[6-Allyl-7-(1,1-dimethyl-allyloxy)-benzo[1,3]dioxol-5-yloxy]-tert-butyl-diphenyl-silane
CAS No.:292073-83-7
Molecular Formula:C₃₁H₃₆O₄Si
Molecular Weight:500.71
Hs Code.:

Synonyms:[6-Allyl-7-(1,1-dimethyl-allyloxy)-benzo[1,3]dioxol-5-yloxy]-tert-butyl-diphenyl-silane

Suppliers and Price of [6-Allyl-7-(1,1-dimethyl-allyloxy)-benzo[1,3]dioxol-5-yloxy]-tert-butyl-diphenyl-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [6-Allyl-7-(1,1-dimethyl-allyloxy)-benzo[1,3]dioxol-5-yloxy]-tert-butyl-diphenyl-silane

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of [6-Allyl-7-(1,1-dimethyl-allyloxy)-benzo[1,3]dioxol-5-yloxy]-tert-butyl-diphenyl-silane

There total 13 articles about [6-Allyl-7-(1,1-dimethyl-allyloxy)-benzo[1,3]dioxol-5-yloxy]-tert-butyl-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 292073-82-6
[6-Allyl-7-(1,1-dimethyl-prop-2-ynyloxy)-benzo[1,3]dioxol-5-yloxy]-tert-butyl-diphenyl-silane

: 292073-83-7
[6-Allyl-7-(1,1-dimethyl-allyloxy)-benzo[1,3]dioxol-5-yloxy]-tert-butyl-diphenyl-silane

Guidance literature:: With quinoline; hydrogen; 10percent Pd-CaCO₃; In ethyl acetate; for 2h;
DOI:10.1021/ja000521m

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 292073-83-7
[6-Allyl-7-(1,1-dimethyl-allyloxy)-benzo[1,3]dioxol-5-yloxy]-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / imidazole; dimethylaminopyridine / CH₂Cl₂ / 12 h / 20 °C

2: 99 percent / H₂; quinoline / 10percent Pd-CaCO₃ / ethyl acetate / 2 h

With 1H-imidazole; quinoline; dmap; hydrogen; 10percent Pd-CaCO₃; In dichloromethane; ethyl acetate; 1: Silylation / 2: Catalytic hydrogenation;
DOI:10.1021/ja000521m

Reference yield:

: 116119-01-8
methyl 7-hydroxybenzo[d][1,3]dioxole-5-carboxylate

: 292073-83-7
[6-Allyl-7-(1,1-dimethyl-allyloxy)-benzo[1,3]dioxol-5-yloxy]-tert-butyl-diphenyl-silane

Guidance literature:: Multi-step reaction with 9 steps

1: 87 percent / K₂CO₃; KI / acetone / 12 h / 20 °C

2: toluene / 12 h / 165 °C

3: K₂CO₃ / acetone / Heating

4: 86 percent / Na-Hg / methanol; ethyl acetate / 12 h / -20 °C

5: 90 percent / LiBr / tetrahydrofuran / 12 h / -78 - 0 °C

6: DBU; CuCl₂*H₂O / acetonitrile / 24 h / 20 °C

7: 85 percent / H₂SO₄; aq. H₂O₂ / CH₂Cl₂ / 0.17 h / 0 °C

8: 97 percent / imidazole; dimethylaminopyridine / CH₂Cl₂ / 12 h / 20 °C

9: 99 percent / H₂; quinoline / 10percent Pd-CaCO₃ / ethyl acetate / 2 h

With 1H-imidazole; quinoline; dmap; sodium amalgam; sulfuric acid; hydrogen; dihydrogen peroxide; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; potassium iodide; lithium bromide; 10percent Pd-CaCO₃; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; acetone; toluene; acetonitrile; 1: Alkylation / 2: Claisen rearrangement / 3: Addition / 4: Elimination / 5: Methylation / 6: Addition / 7: Oxidation; Rearrangement / 8: Silylation / 9: Catalytic hydrogenation;
DOI:10.1021/ja000521m